cis-Cycloheptane-1,2-diol

The title compound, C7H14O2, is a vicinal diol derived from cycloheptane with cis-orientated hydroxy groups. The molecules shows no non-crystallographic symmetry. The O—C—C—O torsion angles of both molecules present in the asymmetric unit [−66....

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Bibliographic Details
Main Authors: Peter Mayer, Peter Klüfers, Richard Betz
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680905051X
Description
Summary:The title compound, C7H14O2, is a vicinal diol derived from cycloheptane with cis-orientated hydroxy groups. The molecules shows no non-crystallographic symmetry. The O—C—C—O torsion angles of both molecules present in the asymmetric unit [−66.4 (2) and −66.9 (2)°] are similar to those in trans-configured cyclohexane derivatives (including pyranoses) as well as rac-trans-cycloheptane-1,2-diol, but smaller than those in trans-configured cyclopentane derivatives (including furanoses). In the crystal structure, O—H...O hydrogen bonds furnish the formation of sheets parallel to [110].
ISSN:1600-5368