The thermal stability of poly(methyl methacrylate) prepared by raft polymerisation
Poly(methyl methacrylate), PMMA, was prepared by reversible addition-fragmentation chain transfer, RAFT, polymerisation using 2-(2-cyanopropyl)-dithiobenzoate, CPDB, as the RAFT agent. The thermal stability of the resulting polymer approached that of anionically prepared PMMA, as determined by therm...
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Serbian Chemical Society
2008-01-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2008/0352-51390809915K.pdf |
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doaj-d9227a4f74d6444eae10bfb7b8945e412020-12-30T07:55:22ZengSerbian Chemical Society Journal of the Serbian Chemical Society0352-51391820-74212008-01-01738-991592110.2298/JSC0809915K0352-51390809915KThe thermal stability of poly(methyl methacrylate) prepared by raft polymerisationKatsikas Lynne0Avramović Milena1Cortés Betancourt Darío Rubén2Milovanović Miloš3Kalagasidis-Krušić Melina T.4Popović Ivanka G.5Tehnološko-metalurški fakultet, BeogradTehnološko-metalurški fakultet, BeogradTehnološko-metalurški fakultet, BeogradInstitut za hemiju, tehnologiju i metalurgiju, BeogradTehnološko-metalurški fakultet, BeogradTehnološko-metalurški fakultet, BeogradPoly(methyl methacrylate), PMMA, was prepared by reversible addition-fragmentation chain transfer, RAFT, polymerisation using 2-(2-cyanopropyl)-dithiobenzoate, CPDB, as the RAFT agent. The thermal stability of the resulting polymer approached that of anionically prepared PMMA, as determined by thermogravimetry. This was the consequence of the RAFT prepared polymer having no head-to-head links and no chain end double bonds, which are responsible for the relatively low thermal stability of radically prepared PMMA.http://www.doiserbia.nb.rs/img/doi/0352-5139/2008/0352-51390809915K.pdfthermogravimetrystabilityraftpmma |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Katsikas Lynne Avramović Milena Cortés Betancourt Darío Rubén Milovanović Miloš Kalagasidis-Krušić Melina T. Popović Ivanka G. |
| spellingShingle |
Katsikas Lynne Avramović Milena Cortés Betancourt Darío Rubén Milovanović Miloš Kalagasidis-Krušić Melina T. Popović Ivanka G. The thermal stability of poly(methyl methacrylate) prepared by raft polymerisation Journal of the Serbian Chemical Society thermogravimetry stability raft pmma |
| author_facet |
Katsikas Lynne Avramović Milena Cortés Betancourt Darío Rubén Milovanović Miloš Kalagasidis-Krušić Melina T. Popović Ivanka G. |
| author_sort |
Katsikas Lynne |
| title |
The thermal stability of poly(methyl methacrylate) prepared by raft polymerisation |
| title_short |
The thermal stability of poly(methyl methacrylate) prepared by raft polymerisation |
| title_full |
The thermal stability of poly(methyl methacrylate) prepared by raft polymerisation |
| title_fullStr |
The thermal stability of poly(methyl methacrylate) prepared by raft polymerisation |
| title_full_unstemmed |
The thermal stability of poly(methyl methacrylate) prepared by raft polymerisation |
| title_sort |
thermal stability of poly(methyl methacrylate) prepared by raft polymerisation |
| publisher |
Serbian Chemical Society |
| series |
Journal of the Serbian Chemical Society |
| issn |
0352-5139 1820-7421 |
| publishDate |
2008-01-01 |
| description |
Poly(methyl methacrylate), PMMA, was prepared by reversible addition-fragmentation chain transfer, RAFT, polymerisation using 2-(2-cyanopropyl)-dithiobenzoate, CPDB, as the RAFT agent. The thermal stability of the resulting polymer approached that of anionically prepared PMMA, as determined by thermogravimetry. This was the consequence of the RAFT prepared polymer having no head-to-head links and no chain end double bonds, which are responsible for the relatively low thermal stability of radically prepared PMMA. |
| topic |
thermogravimetry stability raft pmma |
| url |
http://www.doiserbia.nb.rs/img/doi/0352-5139/2008/0352-51390809915K.pdf |
| work_keys_str_mv |
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