Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)]

Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)]

In the title dinuclear CdII complex, [Cd2(C2N4O2)2(C10H8N2)2(H2O)2], each Cd atom is in a slightly distorted octahedral coordination by two N atoms and one O atom of two 1H-tetrazole-5-carboxylate (TZC) ligands, two N atoms of a 2,2′-bipyridyl ligand and one water O atom. The TZC ligan...

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Main Authors: Shuang-Jiao Sun, Ji-Hua Deng, Ti-Lou Liu
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810027613
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spelling doaj-d975628343f24fdf8140e12abbdc4ab72020-11-24T22:09:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m981m98210.1107/S1600536810027613Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)]Shuang-Jiao SunJi-Hua DengTi-Lou LiuIn the title dinuclear CdII complex, [Cd2(C2N4O2)2(C10H8N2)2(H2O)2], each Cd atom is in a slightly distorted octahedral coordination by two N atoms and one O atom of two 1H-tetrazole-5-carboxylate (TZC) ligands, two N atoms of a 2,2′-bipyridyl ligand and one water O atom. The TZC ligand acts in a tridentate N,O-chelating N-bridging mode to two symmetry-equivalent CdII atoms. The complex reveals molecular Ci symmetry. Extensive O—H...O hydrogen bonding plays an important role in the crystal packing. http://scripts.iucr.org/cgi-bin/paper?S1600536810027613
collection DOAJ
language English
format Article
sources DOAJ
author Shuang-Jiao Sun
Ji-Hua Deng
Ti-Lou Liu
spellingShingle Shuang-Jiao Sun
Ji-Hua Deng
Ti-Lou Liu
Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)]
Acta Crystallographica Section E
author_facet Shuang-Jiao Sun
Ji-Hua Deng
Ti-Lou Liu
author_sort Shuang-Jiao Sun
title Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)]
title_short Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)]
title_full Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)]
title_fullStr Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)]
title_full_unstemmed Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)]
title_sort bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-08-01
description In the title dinuclear CdII complex, [Cd2(C2N4O2)2(C10H8N2)2(H2O)2], each Cd atom is in a slightly distorted octahedral coordination by two N atoms and one O atom of two 1H-tetrazole-5-carboxylate (TZC) ligands, two N atoms of a 2,2′-bipyridyl ligand and one water O atom. The TZC ligand acts in a tridentate N,O-chelating N-bridging mode to two symmetry-equivalent CdII atoms. The complex reveals molecular Ci symmetry. Extensive O—H...O hydrogen bonding plays an important role in the crystal packing.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810027613
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AT jihuadeng bisamp9565carboxylatotetrazolidobisaqua22amp8242bipyridylcadmiumii
AT tilouliu bisamp9565carboxylatotetrazolidobisaqua22amp8242bipyridylcadmiumii
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