Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)]
In the title dinuclear CdII complex, [Cd2(C2N4O2)2(C10H8N2)2(H2O)2], each Cd atom is in a slightly distorted octahedral coordination by two N atoms and one O atom of two 1H-tetrazole-5-carboxylate (TZC) ligands, two N atoms of a 2,2′-bipyridyl ligand and one water O atom. The TZC ligan...
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International Union of Crystallography
2010-08-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810027613 |
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doaj-d975628343f24fdf8140e12abbdc4ab72020-11-24T22:09:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m981m98210.1107/S1600536810027613Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)]Shuang-Jiao SunJi-Hua DengTi-Lou LiuIn the title dinuclear CdII complex, [Cd2(C2N4O2)2(C10H8N2)2(H2O)2], each Cd atom is in a slightly distorted octahedral coordination by two N atoms and one O atom of two 1H-tetrazole-5-carboxylate (TZC) ligands, two N atoms of a 2,2′-bipyridyl ligand and one water O atom. The TZC ligand acts in a tridentate N,O-chelating N-bridging mode to two symmetry-equivalent CdII atoms. The complex reveals molecular Ci symmetry. Extensive O—H...O hydrogen bonding plays an important role in the crystal packing. http://scripts.iucr.org/cgi-bin/paper?S1600536810027613 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Shuang-Jiao Sun Ji-Hua Deng Ti-Lou Liu |
spellingShingle |
Shuang-Jiao Sun Ji-Hua Deng Ti-Lou Liu Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)] Acta Crystallographica Section E |
author_facet |
Shuang-Jiao Sun Ji-Hua Deng Ti-Lou Liu |
author_sort |
Shuang-Jiao Sun |
title |
Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)] |
title_short |
Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)] |
title_full |
Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)] |
title_fullStr |
Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)] |
title_full_unstemmed |
Bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(II)] |
title_sort |
bis(μ-5-carboxylatotetrazolido)bis[aqua(2,2′-bipyridyl)cadmium(ii)] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2010-08-01 |
description |
In the title dinuclear CdII complex, [Cd2(C2N4O2)2(C10H8N2)2(H2O)2], each Cd atom is in a slightly distorted octahedral coordination by two N atoms and one O atom of two 1H-tetrazole-5-carboxylate (TZC) ligands, two N atoms of a 2,2′-bipyridyl ligand and one water O atom. The TZC ligand acts in a tridentate N,O-chelating N-bridging mode to two symmetry-equivalent CdII atoms. The complex reveals molecular Ci symmetry. Extensive O—H...O hydrogen bonding plays an important role in the crystal packing. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810027613 |
work_keys_str_mv |
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1725810979920412672 |