Summary: | The asymmetric unit of the title salt, [Ag(C14H14N4O2)1.5](CF3SO3), comprises a Ag+ cation, three half-molecules of N,N′-bis(2-pyridylmethyl)oxalamide (each of which is disposed about a centre of inversion) and a trifluoromethanesulfonate anion. Distinct coordination modes are found for the bridging ligands, i.e., a μ2,κ2-bridging mode involving pyridine N atoms for one ligand, and a μ2,κ4-bridging mode, employing both pyridine N and amide O atoms for the remaining ligands. The Ag+ cations, which are in a distorted square-pyramidal coordination, and the ligands combine to form a two-dimensional array parallel to (101); these arrays are connected into a three-dimensional structure by trifluoromethanesulfonate anions via N—H...O, C—H...O, and C—F...O interactions.
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