Poly[[bis[μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ4N,O:N′,O′][μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ2N:N′]disilver(I)] bis(trifluoromethanesulfonate)]

Poly[[bis[μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ4N,O:N′,O′][μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ2N:N′]disilver(I)] bis(trifluoromethanesulfonate)]

The asymmetric unit of the title salt, [Ag(C14H14N4O2)1.5](CF3SO3), comprises a Ag+ cation, three half-molecules of N,N′-bis(2-pyridylmethyl)oxalamide (each of which is disposed about a centre of inversion) and a trifluoromethanesulfonate anion. Distinct coordination modes are found fo...

Full description

Bibliographic Details
Main Authors: Hadi D. Arman, Tyler Miller, Pavel Poplaukhin, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810033611
id doaj-d97c445ab5474a558c40670d98361e43
record_format Article
spelling doaj-d97c445ab5474a558c40670d98361e432020-11-24T21:26:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1167m116810.1107/S1600536810033611Poly[[bis[μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ4N,O:N′,O′][μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ2N:N′]disilver(I)] bis(trifluoromethanesulfonate)]Hadi D. ArmanTyler MillerPavel PoplaukhinEdward R. T. TiekinkThe asymmetric unit of the title salt, [Ag(C14H14N4O2)1.5](CF3SO3), comprises a Ag+ cation, three half-molecules of N,N′-bis(2-pyridylmethyl)oxalamide (each of which is disposed about a centre of inversion) and a trifluoromethanesulfonate anion. Distinct coordination modes are found for the bridging ligands, i.e., a μ2,κ2-bridging mode involving pyridine N atoms for one ligand, and a μ2,κ4-bridging mode, employing both pyridine N and amide O atoms for the remaining ligands. The Ag+ cations, which are in a distorted square-pyramidal coordination, and the ligands combine to form a two-dimensional array parallel to (101); these arrays are connected into a three-dimensional structure by trifluoromethanesulfonate anions via N—H...O, C—H...O, and C—F...O interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536810033611
collection DOAJ
language English
format Article
sources DOAJ
author Hadi D. Arman
Tyler Miller
Pavel Poplaukhin
Edward R. T. Tiekink
spellingShingle Hadi D. Arman
Tyler Miller
Pavel Poplaukhin
Edward R. T. Tiekink
Poly[[bis[μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ4N,O:N′,O′][μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ2N:N′]disilver(I)] bis(trifluoromethanesulfonate)]
Acta Crystallographica Section E
author_facet Hadi D. Arman
Tyler Miller
Pavel Poplaukhin
Edward R. T. Tiekink
author_sort Hadi D. Arman
title Poly[[bis[μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ4N,O:N′,O′][μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ2N:N′]disilver(I)] bis(trifluoromethanesulfonate)]
title_short Poly[[bis[μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ4N,O:N′,O′][μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ2N:N′]disilver(I)] bis(trifluoromethanesulfonate)]
title_full Poly[[bis[μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ4N,O:N′,O′][μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ2N:N′]disilver(I)] bis(trifluoromethanesulfonate)]
title_fullStr Poly[[bis[μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ4N,O:N′,O′][μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ2N:N′]disilver(I)] bis(trifluoromethanesulfonate)]
title_full_unstemmed Poly[[bis[μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ4N,O:N′,O′][μ2-N,N′-bis(2-pyridylmethyl)oxalamide-κ2N:N′]disilver(I)] bis(trifluoromethanesulfonate)]
title_sort poly[[bis[μ2-n,n′-bis(2-pyridylmethyl)oxalamide-κ4n,o:n′,o′][μ2-n,n′-bis(2-pyridylmethyl)oxalamide-κ2n:n′]disilver(i)] bis(trifluoromethanesulfonate)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-09-01
description The asymmetric unit of the title salt, [Ag(C14H14N4O2)1.5](CF3SO3), comprises a Ag+ cation, three half-molecules of N,N′-bis(2-pyridylmethyl)oxalamide (each of which is disposed about a centre of inversion) and a trifluoromethanesulfonate anion. Distinct coordination modes are found for the bridging ligands, i.e., a μ2,κ2-bridging mode involving pyridine N atoms for one ligand, and a μ2,κ4-bridging mode, employing both pyridine N and amide O atoms for the remaining ligands. The Ag+ cations, which are in a distorted square-pyramidal coordination, and the ligands combine to form a two-dimensional array parallel to (101); these arrays are connected into a three-dimensional structure by trifluoromethanesulfonate anions via N—H...O, C—H...O, and C—F...O interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810033611
work_keys_str_mv AT hadidarman polybisamp9562nnamp8242bis2pyridylmethyloxalamideamp9544nonamp8242oamp8242amp9562nnamp8242bis2pyridylmethyloxalamideamp9542nnamp8242disilveribistrifluoromethanesulfonate
AT tylermiller polybisamp9562nnamp8242bis2pyridylmethyloxalamideamp9544nonamp8242oamp8242amp9562nnamp8242bis2pyridylmethyloxalamideamp9542nnamp8242disilveribistrifluoromethanesulfonate
AT pavelpoplaukhin polybisamp9562nnamp8242bis2pyridylmethyloxalamideamp9544nonamp8242oamp8242amp9562nnamp8242bis2pyridylmethyloxalamideamp9542nnamp8242disilveribistrifluoromethanesulfonate
AT edwardrttiekink polybisamp9562nnamp8242bis2pyridylmethyloxalamideamp9544nonamp8242oamp8242amp9562nnamp8242bis2pyridylmethyloxalamideamp9542nnamp8242disilveribistrifluoromethanesulfonate
_version_ 1725979465235824640

Similar Items