Analysis of Adsorption and Decomposition of Odour and Tar Components in Tobacco Smoke on Non-Woven Fabric-Supported Photocatalysts

The release of substantial amounts of toxicologically significant, irritant, and malodourous compounds during the complete combustion of tobacco can generate an unpleasant environment, especially indoors. Herein, we developed non-woven fabric-supported UV- and visible-light-responsive photocatalysts...

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Main Authors: Tsuyoshi Ochiai, Daisuke Aoki, Hidenori Saito, Yasuhisa Akutsu, Morio Nagata
Format: Article
Language:English
Published: MDPI AG 2020-03-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/10/3/304
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spelling doaj-d9ac0ffb2581449e93a604a7d5f96f902020-11-25T02:40:34ZengMDPI AGCatalysts2073-43442020-03-0110330410.3390/catal10030304catal10030304Analysis of Adsorption and Decomposition of Odour and Tar Components in Tobacco Smoke on Non-Woven Fabric-Supported PhotocatalystsTsuyoshi Ochiai0Daisuke Aoki1Hidenori Saito2Yasuhisa Akutsu3Morio Nagata4Kawasaki Technical Support Department, Local Independent Administrative Agency Kanagawa Institute of Industrial Science and TEChnology (KISTEC), Ground Floor East Wing, Innovation Center Building, KSP, 3-2-1 Sakado, Takatsu-ku, Kawasaki, Kanagawa 213-0012, JapanKawasaki Technical Support Department, Local Independent Administrative Agency Kanagawa Institute of Industrial Science and TEChnology (KISTEC), Ground Floor East Wing, Innovation Center Building, KSP, 3-2-1 Sakado, Takatsu-ku, Kawasaki, Kanagawa 213-0012, JapanKawasaki Technical Support Department, Local Independent Administrative Agency Kanagawa Institute of Industrial Science and TEChnology (KISTEC), Ground Floor East Wing, Innovation Center Building, KSP, 3-2-1 Sakado, Takatsu-ku, Kawasaki, Kanagawa 213-0012, JapanKawasaki Technical Support Department, Local Independent Administrative Agency Kanagawa Institute of Industrial Science and TEChnology (KISTEC), Ground Floor East Wing, Innovation Center Building, KSP, 3-2-1 Sakado, Takatsu-ku, Kawasaki, Kanagawa 213-0012, JapanDepartment of Industrial Chemistry, Graduate School of Engineering, Tokyo University of Science, 12-1 Ichigayafunagawara-cho, Shinjuku-ku, Tokyo 162-0826, JapanThe release of substantial amounts of toxicologically significant, irritant, and malodourous compounds during the complete combustion of tobacco can generate an unpleasant environment, especially indoors. Herein, we developed non-woven fabric-supported UV- and visible-light-responsive photocatalysts capable of adsorbing and decomposing the odour and tar components of tobacco smoke under irradiation with UV or visible light. The processes of odour component adsorption and subsequent decomposition under irradiation were evaluated in terms of colour changes in the catalytic system and by gas chromatography&#8722;mass spectrometry. By considering three different photocatalysts, namely TiO<sub>2</sub>, Fe(III)-grafted TiO<sub>2</sub>, and Cu(II)-grafted WO<sub>3</sub>, we assessed the magnitude of odour and tar component adsorption on the fabric fibres, as well as the decomposition of these species after specific visible light or UV irradiation periods. Considering the expansion of our technology for practical applications, the best results among the three tested materials were obtained for non-woven fabric-supported Fe/TiO<sub>2</sub>. We believe that our technology can be implemented in the design of interior decoration materials for creating a comfortable environment.https://www.mdpi.com/2073-4344/10/3/304photocatalysttio<sub>2</sub>fe/tio<sub>2</sub>cu/wo<sub>3</sub>non-woven fabricadsorptiontobacco smoke contaminationthird-hand smoke
collection DOAJ
language English
format Article
sources DOAJ
author Tsuyoshi Ochiai
Daisuke Aoki
Hidenori Saito
Yasuhisa Akutsu
Morio Nagata
spellingShingle Tsuyoshi Ochiai
Daisuke Aoki
Hidenori Saito
Yasuhisa Akutsu
Morio Nagata
Analysis of Adsorption and Decomposition of Odour and Tar Components in Tobacco Smoke on Non-Woven Fabric-Supported Photocatalysts
Catalysts
photocatalyst
tio<sub>2</sub>
fe/tio<sub>2</sub>
cu/wo<sub>3</sub>
non-woven fabric
adsorption
tobacco smoke contamination
third-hand smoke
author_facet Tsuyoshi Ochiai
Daisuke Aoki
Hidenori Saito
Yasuhisa Akutsu
Morio Nagata
author_sort Tsuyoshi Ochiai
title Analysis of Adsorption and Decomposition of Odour and Tar Components in Tobacco Smoke on Non-Woven Fabric-Supported Photocatalysts
title_short Analysis of Adsorption and Decomposition of Odour and Tar Components in Tobacco Smoke on Non-Woven Fabric-Supported Photocatalysts
title_full Analysis of Adsorption and Decomposition of Odour and Tar Components in Tobacco Smoke on Non-Woven Fabric-Supported Photocatalysts
title_fullStr Analysis of Adsorption and Decomposition of Odour and Tar Components in Tobacco Smoke on Non-Woven Fabric-Supported Photocatalysts
title_full_unstemmed Analysis of Adsorption and Decomposition of Odour and Tar Components in Tobacco Smoke on Non-Woven Fabric-Supported Photocatalysts
title_sort analysis of adsorption and decomposition of odour and tar components in tobacco smoke on non-woven fabric-supported photocatalysts
publisher MDPI AG
series Catalysts
issn 2073-4344
publishDate 2020-03-01
description The release of substantial amounts of toxicologically significant, irritant, and malodourous compounds during the complete combustion of tobacco can generate an unpleasant environment, especially indoors. Herein, we developed non-woven fabric-supported UV- and visible-light-responsive photocatalysts capable of adsorbing and decomposing the odour and tar components of tobacco smoke under irradiation with UV or visible light. The processes of odour component adsorption and subsequent decomposition under irradiation were evaluated in terms of colour changes in the catalytic system and by gas chromatography&#8722;mass spectrometry. By considering three different photocatalysts, namely TiO<sub>2</sub>, Fe(III)-grafted TiO<sub>2</sub>, and Cu(II)-grafted WO<sub>3</sub>, we assessed the magnitude of odour and tar component adsorption on the fabric fibres, as well as the decomposition of these species after specific visible light or UV irradiation periods. Considering the expansion of our technology for practical applications, the best results among the three tested materials were obtained for non-woven fabric-supported Fe/TiO<sub>2</sub>. We believe that our technology can be implemented in the design of interior decoration materials for creating a comfortable environment.
topic photocatalyst
tio<sub>2</sub>
fe/tio<sub>2</sub>
cu/wo<sub>3</sub>
non-woven fabric
adsorption
tobacco smoke contamination
third-hand smoke
url https://www.mdpi.com/2073-4344/10/3/304
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