Effect of High Temperature Sodium Hydroxide Immersion on Fusion Bond Epoxy Coating

• Main Authors: Amal Al-Borno, Xianyi Chen, Shailesh Kewaldas Dhoke
• Format: Article
• Language: English
• Published: Hindawi Limited 2015-01-01
• Series: International Journal of Corrosion
• Online Access: http://dx.doi.org/10.1155/2015/903478

Fusion Bond Epoxy (FBE) coating system was exposed to 5% sodium hydroxide at elevated temperature for 30 days. The result of exposure showed formation of adhere deposit layer, a discolored zone underneath and remaining un-affected bulk of the coating. The deterioration of the coating was characterized using analytical techniques like scanning electron microscopy (SEM), energy-dispersive X-ray (EDAX) spectroscopy, attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR), differential scanning calorimetry (DSC), pull-off adhesion, and electrochemical impedance spectroscopy (EIS). Results obtained indicated chemical deterioration of the coating in the discolored zone and leaching of low molecular weight coating component forming deposit layer. Although the adhesion strength and barrier property were not affected, the polymer matrix in the affected zone undergoes severe changes in its surface microstructure, primary chemical structure, and glass transition temperature. This may inflict serious impairment of the coating functional properties and premature failure of the coating in long term exposure.