1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one
The title ferrocene derivative, [Fe(C5H5)(C14H13FNO)], crystallizes in the same space group with similar unit-cell parameters as the derivatives 3-anilino-1-ferrocenylpropan-1-one [Leka et al. (2012). Acta Cryst. E68, m229] and 1-ferrocenyl-3-(4-methylanilino)propan-1-one [Leka et al. (2012). Acta C...
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International Union of Crystallography
2012-02-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812003510 |
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doaj-da62d5579781407ebbc8f56ade74c8682020-11-25T00:49:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m231m23110.1107/S16005368120035101-Ferrocenyl-3-(3-fluoroanilino)propan-1-oneZorica LekaSladjana B. NovakovićAnka PejovićGoran A. BogdanovićRastko D. VukićevićThe title ferrocene derivative, [Fe(C5H5)(C14H13FNO)], crystallizes in the same space group with similar unit-cell parameters as the derivatives 3-anilino-1-ferrocenylpropan-1-one [Leka et al. (2012). Acta Cryst. E68, m229] and 1-ferrocenyl-3-(4-methylanilino)propan-1-one [Leka et al. (2012). Acta Cryst. E68, m230]. The dihedral angle between the best planes of the benzene ring and the substituted cyclopentadienyl ring is 83.4 (1)°. The presence of the electronegative fluoro substituent in the meta position of the aniline group does not alter the crystal packing compared to the other two derivatives. The molecules are connected into centrosymmetric dimers via N—H...O hydrogen bonds. In addition, C—H...O and C—H...N contacts stabilize the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536812003510 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Zorica Leka Sladjana B. Novaković Anka Pejović Goran A. Bogdanović Rastko D. Vukićević |
spellingShingle |
Zorica Leka Sladjana B. Novaković Anka Pejović Goran A. Bogdanović Rastko D. Vukićević 1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one Acta Crystallographica Section E |
author_facet |
Zorica Leka Sladjana B. Novaković Anka Pejović Goran A. Bogdanović Rastko D. Vukićević |
author_sort |
Zorica Leka |
title |
1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one |
title_short |
1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one |
title_full |
1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one |
title_fullStr |
1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one |
title_full_unstemmed |
1-Ferrocenyl-3-(3-fluoroanilino)propan-1-one |
title_sort |
1-ferrocenyl-3-(3-fluoroanilino)propan-1-one |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2012-02-01 |
description |
The title ferrocene derivative, [Fe(C5H5)(C14H13FNO)], crystallizes in the same space group with similar unit-cell parameters as the derivatives 3-anilino-1-ferrocenylpropan-1-one [Leka et al. (2012). Acta Cryst. E68, m229] and 1-ferrocenyl-3-(4-methylanilino)propan-1-one [Leka et al. (2012). Acta Cryst. E68, m230]. The dihedral angle between the best planes of the benzene ring and the substituted cyclopentadienyl ring is 83.4 (1)°. The presence of the electronegative fluoro substituent in the meta position of the aniline group does not alter the crystal packing compared to the other two derivatives. The molecules are connected into centrosymmetric dimers via N—H...O hydrogen bonds. In addition, C—H...O and C—H...N contacts stabilize the crystal packing. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536812003510 |
work_keys_str_mv |
AT zoricaleka 1ferrocenyl33fluoroanilinopropan1one AT sladjanabnovakoviamp263 1ferrocenyl33fluoroanilinopropan1one AT ankapejoviamp263 1ferrocenyl33fluoroanilinopropan1one AT goranabogdanoviamp263 1ferrocenyl33fluoroanilinopropan1one AT rastkodvukiamp263eviamp263 1ferrocenyl33fluoroanilinopropan1one |
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