Composition Distribution, Damping and Thermal Properties of the Thickness-Continuous Gradient Epoxy/Polyurethane Interpenetrating Polymer Networks

A thickness gradient interpenetrating polymer network (IPN) was easily created that takes advantage of the relatively poor compatibility and curing rates discrepancy between epoxy (EP) and polyurethane (PU). Ultraviolet absorption spectrum (UV-Vis), thermogravimetric (TG), Differential scanning calo...

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Bibliographic Details
Main Authors: Xuesong Lv, Zhixiong Huang, Minxian Shi, Yun Fan, Guanbin Gao
Format: Article
Language:English
Published: MDPI AG 2017-01-01
Series:Applied Sciences
Subjects:
Online Access:http://www.mdpi.com/2076-3417/7/2/135
Description
Summary:A thickness gradient interpenetrating polymer network (IPN) was easily created that takes advantage of the relatively poor compatibility and curing rates discrepancy between epoxy (EP) and polyurethane (PU). Ultraviolet absorption spectrum (UV-Vis), thermogravimetric (TG), Differential scanning calorimetry (DSC), Dynamic thermomechanical analysis (DMA), Atomic force microscope (AFM) and water contact angle were adopted to characterize this IPN structure. We found that the absorption in visible light region, glass-transition temperatures (Tg), thermal decomposition temperatures (Td) and Derjaguin–Muller–Toporov (DMT) modulus were increasing along with the gradient direction from bottom side to top side of the IPN. While the absorption in ultraviolet region and adhesion force were decreasing along with the gradient direction from bottom side to top side of the IPN. DMA analysis demonstrates that this continuous gradient IPN has a good balance between the damping temperature range and the loss factor which is suitable for using as a self-supporting damping structure.
ISSN:2076-3417