OXIDATION OF PHENOL IN AQUEOUS SOLUTION WITH COPPER OXIDE CATALYSTS SUPPORTED ON γ-Al2O3, PILLARED CLAY AND TiO2: COMPARISON OF THE PERFORMANCE AND COSTS ASSOCIATED WITH EACH CATALYST

• Main Authors: C. A. Pires, A. C. C. dos Santos, E. Jordão
• Format: Article
• Language: English
• Published: Brazilian Society of Chemical Engineering 2015-12-01
• Series: Brazilian Journal of Chemical Engineering
• Subjects: Phenol; Oxidation; CuO; Pillared clay; TiO2; Costs
• Online Access: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-66322015000400837&lng=en&tlng=en

Abstract The Catalytic Wet Air Oxidation (CWAO) of phenol using copper oxide catalysts supported by γ-Al2O3, TiO2, and pillared clay was evaluated to identify which of these catalysts was the most appropriate for this reaction. The CuO/PILC, CuO/γ-Al2O3 and CuO/TiO2 catalysts were the most successful at removing phenol and resulted in more than 96% conversion. Among these catalysts, CuO/γ-Al2O3 produced the largest amount of CO2, the lowest amount of intermediate products and the lowest amount of copper leaching. These results showed that the CuO/γ-Al2O3catalyst was the best for the end of the reaction. However, the methods used in this study did not allow us to identify the most appropriate reaction time (or catalyst). An alternative approach for this problem was to quantify the costs for each reaction time. Using this approach, the CuO/γ-Al2O3 catalyst was the most economically favorable catalyst when it was used during the first hour of the reaction.