[N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ2N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1)
In the title co-crystal, [Mo(C14H9ClN2O4)O2(CH3OH)]·C10H8N2, the deprotonated Schiff base O,N,O′-chelates to the MoVI atom, the three atoms involved in chelation comprising the fac sites of the octahedron surrounding the methanol-coordinated metal atom. The methanol molecu...
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International Union of Crystallography
2011-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811017259 |
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doaj-dd16da824c854f28951890b4c5a062fc2020-11-25T02:16:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676m747m74710.1107/S1600536811017259[N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ2N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1)Ngui Khiong NganRichard Chee Seng WongKong Mun LoSeik Weng NgIn the title co-crystal, [Mo(C14H9ClN2O4)O2(CH3OH)]·C10H8N2, the deprotonated Schiff base O,N,O′-chelates to the MoVI atom, the three atoms involved in chelation comprising the fac sites of the octahedron surrounding the methanol-coordinated metal atom. The methanol molecule forms an O—H...N hydrogen bond to an N atom of the 4,4′-bipyridine solvent molecule; the hydroxy group of the Schiff base forms an O—H...N hydrogen bond to the other N atom of another molecule. The two hydrogen bonds leading to the formation of a helical chain running along the b axis.http://scripts.iucr.org/cgi-bin/paper?S1600536811017259 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Ngui Khiong Ngan Richard Chee Seng Wong Kong Mun Lo Seik Weng Ng |
| spellingShingle |
Ngui Khiong Ngan Richard Chee Seng Wong Kong Mun Lo Seik Weng Ng [N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ2N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) Acta Crystallographica Section E |
| author_facet |
Ngui Khiong Ngan Richard Chee Seng Wong Kong Mun Lo Seik Weng Ng |
| author_sort |
Ngui Khiong Ngan |
| title |
[N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ2N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) |
| title_short |
[N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ2N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) |
| title_full |
[N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ2N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) |
| title_fullStr |
[N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ2N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) |
| title_full_unstemmed |
[N′-(5-Chloro-2-oxidobenzyl-κO)-2,4-dihydroxybenzohydrazidato-κ2N′,O](methanol-κO)dioxidomolybdenum(VI)–4,4′-bipyridine (1/1) |
| title_sort |
[n′-(5-chloro-2-oxidobenzyl-κo)-2,4-dihydroxybenzohydrazidato-κ2n′,o](methanol-κo)dioxidomolybdenum(vi)–4,4′-bipyridine (1/1) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-06-01 |
| description |
In the title co-crystal, [Mo(C14H9ClN2O4)O2(CH3OH)]·C10H8N2, the deprotonated Schiff base O,N,O′-chelates to the MoVI atom, the three atoms involved in chelation comprising the fac sites of the octahedron surrounding the methanol-coordinated metal atom. The methanol molecule forms an O—H...N hydrogen bond to an N atom of the 4,4′-bipyridine solvent molecule; the hydroxy group of the Schiff base forms an O—H...N hydrogen bond to the other N atom of another molecule. The two hydrogen bonds leading to the formation of a helical chain running along the b axis. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811017259 |
| work_keys_str_mv |
AT nguikhiongngan namp82425chloro2oxidobenzylamp954o24dihydroxybenzohydrazidatoamp9542namp8242omethanolamp954odioxidomolybdenumviamp821144amp8242bipyridine11 AT richardcheesengwong namp82425chloro2oxidobenzylamp954o24dihydroxybenzohydrazidatoamp9542namp8242omethanolamp954odioxidomolybdenumviamp821144amp8242bipyridine11 AT kongmunlo namp82425chloro2oxidobenzylamp954o24dihydroxybenzohydrazidatoamp9542namp8242omethanolamp954odioxidomolybdenumviamp821144amp8242bipyridine11 AT seikwengng namp82425chloro2oxidobenzylamp954o24dihydroxybenzohydrazidatoamp9542namp8242omethanolamp954odioxidomolybdenumviamp821144amp8242bipyridine11 |
| _version_ |
1724889018612580352 |