Temporally and Spatially Resolved Emission Spectroscopy of Hydrogen, Cyanide and Carbon in Laser-Induced Plasma

• Main Authors: Christian G. Parigger, Christopher M. Helstern, Ghaneshwar Gautam
• Format: Article
• Language: English
• Published: MDPI AG 2019-08-01
• Series: Atoms
• Subjects: laser-induced plasma; atomic spectroscopy; molecular spectroscopy; cyanide; hydrogen; carbon
• Online Access: https://www.mdpi.com/2218-2004/7/3/74

In this study, we examine the atomic and molecular signatures in laser-induced plasma. Abel inversions of measured line-of-sight data reveal insight into the radial plasma distribution. Laser-plasma is generated with 6 ns, Q-switched Nd:YAG radiation with energies in the range of 100 to 800 mJ. Temporally- and spatially-resolved emission spectroscopy investigates expansion dynamics. Specific interests include atomic hydrogen (H) and cyanide (CN). Atomic hydrogen spectra indicate axisymmetric shell structures and isentropic expansion of the plasma kernel. The recombination radiation of CN emanates within the first 100 nanoseconds for laser-induced breakdown in a 1:1 mole ratio CO₂:N₂ gas mixture. CN excitation temperatures are determined from fitting recorded and computed spectra. Chemical equilibrium mole fractions of CN are computed for air and the CO₂:N₂ gas mixture. Measurements utilize a 0.64-m Czerny−Turner type spectrometer and an intensified charge-coupled device.