Construction of C-C bonds via photoreductive coupling of ketones and aldehydes in the metal-organic-framework MFM-300(Cr)

The construction of C-C bonds via reductive coupling carbonyl compounds is a huge challenge in organic transformations. Here, the authors develop a highly efficient system for the photoreductive coupling of aldehydes and ketones to the corresponding 1,2-diols under mild conditions.

Bibliographic Details
Main Authors: Tian Luo, Lili Li, Yinlin Chen, Jie An, Chengcheng Liu, Zheng Yan, Joseph H. Carter, Xue Han, Alena M. Sheveleva, Floriana Tuna, Eric J. L. McInnes, Chiu C. Tang, Martin Schröder, Sihai Yang
Format: Article
Language:English
Published: Nature Publishing Group 2021-06-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-021-23302-w
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spelling doaj-e1c602c3bdf2457894897e38db5c41aa2021-06-13T11:16:24ZengNature Publishing GroupNature Communications2041-17232021-06-0112111010.1038/s41467-021-23302-wConstruction of C-C bonds via photoreductive coupling of ketones and aldehydes in the metal-organic-framework MFM-300(Cr)Tian Luo0Lili Li1Yinlin Chen2Jie An3Chengcheng Liu4Zheng Yan5Joseph H. Carter6Xue Han7Alena M. Sheveleva8Floriana Tuna9Eric J. L. McInnes10Chiu C. Tang11Martin Schröder12Sihai Yang13Department of Chemistry, University of ManchesterDepartment of Chemistry, University of ManchesterDepartment of Chemistry, University of ManchesterDepartment of Nutrition and Health, China Agricultural UniversityDepartment of Chemistry, University of ManchesterDepartment of Chemistry, University of ManchesterDepartment of Chemistry, University of ManchesterDepartment of Chemistry, University of ManchesterDepartment of Chemistry, University of ManchesterDepartment of Chemistry, University of ManchesterDepartment of Chemistry, University of ManchesterDiamond Light Source, Harwell Science CampusDepartment of Chemistry, University of ManchesterDepartment of Chemistry, University of ManchesterThe construction of C-C bonds via reductive coupling carbonyl compounds is a huge challenge in organic transformations. Here, the authors develop a highly efficient system for the photoreductive coupling of aldehydes and ketones to the corresponding 1,2-diols under mild conditions.https://doi.org/10.1038/s41467-021-23302-w
collection DOAJ
language English
format Article
sources DOAJ
author Tian Luo
Lili Li
Yinlin Chen
Jie An
Chengcheng Liu
Zheng Yan
Joseph H. Carter
Xue Han
Alena M. Sheveleva
Floriana Tuna
Eric J. L. McInnes
Chiu C. Tang
Martin Schröder
Sihai Yang
spellingShingle Tian Luo
Lili Li
Yinlin Chen
Jie An
Chengcheng Liu
Zheng Yan
Joseph H. Carter
Xue Han
Alena M. Sheveleva
Floriana Tuna
Eric J. L. McInnes
Chiu C. Tang
Martin Schröder
Sihai Yang
Construction of C-C bonds via photoreductive coupling of ketones and aldehydes in the metal-organic-framework MFM-300(Cr)
Nature Communications
author_facet Tian Luo
Lili Li
Yinlin Chen
Jie An
Chengcheng Liu
Zheng Yan
Joseph H. Carter
Xue Han
Alena M. Sheveleva
Floriana Tuna
Eric J. L. McInnes
Chiu C. Tang
Martin Schröder
Sihai Yang
author_sort Tian Luo
title Construction of C-C bonds via photoreductive coupling of ketones and aldehydes in the metal-organic-framework MFM-300(Cr)
title_short Construction of C-C bonds via photoreductive coupling of ketones and aldehydes in the metal-organic-framework MFM-300(Cr)
title_full Construction of C-C bonds via photoreductive coupling of ketones and aldehydes in the metal-organic-framework MFM-300(Cr)
title_fullStr Construction of C-C bonds via photoreductive coupling of ketones and aldehydes in the metal-organic-framework MFM-300(Cr)
title_full_unstemmed Construction of C-C bonds via photoreductive coupling of ketones and aldehydes in the metal-organic-framework MFM-300(Cr)
title_sort construction of c-c bonds via photoreductive coupling of ketones and aldehydes in the metal-organic-framework mfm-300(cr)
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2021-06-01
description The construction of C-C bonds via reductive coupling carbonyl compounds is a huge challenge in organic transformations. Here, the authors develop a highly efficient system for the photoreductive coupling of aldehydes and ketones to the corresponding 1,2-diols under mild conditions.
url https://doi.org/10.1038/s41467-021-23302-w
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