Ba11La4Br34: a new barium lanthanum bromide
The structure of the title compound, barium lanthanum bromide (11/4/34), can be derived from the fluorite structure. The asymmetric unit contains two Ba sites (one with site symmetry 4/m..), one La site (site symmetry 4..), one mixed-occupied Ba and La site (ratio 1:1, site symmetry m..) and six Br...
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International Union of Crystallography
2011-10-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811037354 |
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doaj-e1cdf68a7e684c069cf55d7c0a17d6592020-11-25T01:35:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710i53i5410.1107/S1600536811037354Ba11La4Br34: a new barium lanthanum bromideEdith Bourret-CourchesneGautam GundiahGuang WuYetta EaglemanStephen DerenzoThe structure of the title compound, barium lanthanum bromide (11/4/34), can be derived from the fluorite structure. The asymmetric unit contains two Ba sites (one with site symmetry 4/m..), one La site (site symmetry 4..), one mixed-occupied Ba and La site (ratio 1:1, site symmetry m..) and six Br sites (one with site symmetry =4.., one with 2.., one with m.., the latter being disordered over two positions with a 0.86:0.14 ratio). The fundamental building units of the structure are edge-sharing polyhedral clusters made up of Ba and La bromide clusters interconnected to BaBr8 square prisms and BaBr10 groups.http://scripts.iucr.org/cgi-bin/paper?S1600536811037354 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Edith Bourret-Courchesne Gautam Gundiah Guang Wu Yetta Eagleman Stephen Derenzo |
spellingShingle |
Edith Bourret-Courchesne Gautam Gundiah Guang Wu Yetta Eagleman Stephen Derenzo Ba11La4Br34: a new barium lanthanum bromide Acta Crystallographica Section E |
author_facet |
Edith Bourret-Courchesne Gautam Gundiah Guang Wu Yetta Eagleman Stephen Derenzo |
author_sort |
Edith Bourret-Courchesne |
title |
Ba11La4Br34: a new barium lanthanum bromide |
title_short |
Ba11La4Br34: a new barium lanthanum bromide |
title_full |
Ba11La4Br34: a new barium lanthanum bromide |
title_fullStr |
Ba11La4Br34: a new barium lanthanum bromide |
title_full_unstemmed |
Ba11La4Br34: a new barium lanthanum bromide |
title_sort |
ba11la4br34: a new barium lanthanum bromide |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2011-10-01 |
description |
The structure of the title compound, barium lanthanum bromide (11/4/34), can be derived from the fluorite structure. The asymmetric unit contains two Ba sites (one with site symmetry 4/m..), one La site (site symmetry 4..), one mixed-occupied Ba and La site (ratio 1:1, site symmetry m..) and six Br sites (one with site symmetry =4.., one with 2.., one with m.., the latter being disordered over two positions with a 0.86:0.14 ratio). The fundamental building units of the structure are edge-sharing polyhedral clusters made up of Ba and La bromide clusters interconnected to BaBr8 square prisms and BaBr10 groups. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811037354 |
work_keys_str_mv |
AT edithbourretcourchesne ba11la4br34anewbariumlanthanumbromide AT gautamgundiah ba11la4br34anewbariumlanthanumbromide AT guangwu ba11la4br34anewbariumlanthanumbromide AT yettaeagleman ba11la4br34anewbariumlanthanumbromide AT stephenderenzo ba11la4br34anewbariumlanthanumbromide |
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