Synthesis and catalytic properties of nickel salts of Keggin-type heteropolyacids embedded metal-organic framework hybrid nanocatalyst

• Main Authors: Zhang Qiuyun, Ling Dan, Lei Dandan, Deng Taoli, Zhang Yutao, Ma Peihua
• Format: Article
• Language: English
• Published: De Gruyter 2020-01-01
• Series: Green Processing and Synthesis
• Subjects: heteropolyacid salts; uio-66; nanocatalyst; esterification; biodiesel
• Online Access: https://doi.org/10.1515/gps-2020-0014

Nickel salts of Keggin-type heteropolyacid on Zr(IV)-based metal-organic frameworks (UiO-66) has been synthesized via ion-exchange followed by a facile one-pot hydrothermal method. The synthesized catalysts underwent FT-IR, N2 adsorption-desorption, powder XRD, SEM and TEM analysis. The NiHSiW/UiO-66 catalyst was used as a new and effective solid acid in the catalytic transfer free fatty acid to biodiesel with an optimum conversion of 86.7%. The excellent activity of the NiHSiW/UiO-66 nanocatalyst was closely related to its high specific surface area, nano-sized catalyst, and the synergistic effects of NiHSiW salts and UiO-66 matrix. Importantly, a relatively stable catalytic performance was achieved for 8 repeated cycles. Finally, kinetics of the esterification reaction have been assumed to be of pseudo first order.