Dichloridotris(trimethylphosphine)nickel(II)

Dichloridotris(trimethylphosphine)nickel(II)

The title compound, [NiCl2(C3H9P)3], was obtained as a product of the reaction of [NiCl2(PMe3)2] with an equivalent trimethylphosphine in diethyl ether. It easily loses trimethylphosphine at room temperature to give NiCl2(PMe3)2. There are two independent molecules in the asymmetric unit, and their...

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Main Authors: Hongjian Sun, Qibao Wang, Ruixia Cao
Format: Article
Language:English
Published: International Union of Crystallography 2008-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808000317
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spelling doaj-e206699cd6924c5891563c29de3825a62020-11-24T23:55:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m335m33510.1107/S1600536808000317Dichloridotris(trimethylphosphine)nickel(II)Hongjian SunQibao WangRuixia CaoThe title compound, [NiCl2(C3H9P)3], was obtained as a product of the reaction of [NiCl2(PMe3)2] with an equivalent trimethylphosphine in diethyl ether. It easily loses trimethylphosphine at room temperature to give NiCl2(PMe3)2. There are two independent molecules in the asymmetric unit, and their bond lengths and angles are similar. The Ni environment is trigonal bipyramidal. One Ni, one P and two Cl atoms lie in the equatorial plane, with the remaining two P atoms occupying axial positions. The equatorial Ni—P bond length is shorter than the axial bond lengths.http://scripts.iucr.org/cgi-bin/paper?S1600536808000317
collection DOAJ
language English
format Article
sources DOAJ
author Hongjian Sun
Qibao Wang
Ruixia Cao
spellingShingle Hongjian Sun
Qibao Wang
Ruixia Cao
Dichloridotris(trimethylphosphine)nickel(II)
Acta Crystallographica Section E
author_facet Hongjian Sun
Qibao Wang
Ruixia Cao
author_sort Hongjian Sun
title Dichloridotris(trimethylphosphine)nickel(II)
title_short Dichloridotris(trimethylphosphine)nickel(II)
title_full Dichloridotris(trimethylphosphine)nickel(II)
title_fullStr Dichloridotris(trimethylphosphine)nickel(II)
title_full_unstemmed Dichloridotris(trimethylphosphine)nickel(II)
title_sort dichloridotris(trimethylphosphine)nickel(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-02-01
description The title compound, [NiCl2(C3H9P)3], was obtained as a product of the reaction of [NiCl2(PMe3)2] with an equivalent trimethylphosphine in diethyl ether. It easily loses trimethylphosphine at room temperature to give NiCl2(PMe3)2. There are two independent molecules in the asymmetric unit, and their bond lengths and angles are similar. The Ni environment is trigonal bipyramidal. One Ni, one P and two Cl atoms lie in the equatorial plane, with the remaining two P atoms occupying axial positions. The equatorial Ni—P bond length is shorter than the axial bond lengths.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808000317
work_keys_str_mv AT hongjiansun dichloridotristrimethylphosphinenickelii
AT qibaowang dichloridotristrimethylphosphinenickelii
AT ruixiacao dichloridotristrimethylphosphinenickelii
_version_ 1725462505998778368

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