catena-Poly[4-methylmorpholin-4-ium [[dichloridobismuth(III)]-di-μ-chlorido]]
The asymmetric unit of the title complex, {(C5H12NO)[BiCl4]}n, contains two bridging and two cis non-bridging chloride ligands coordinated to a central BiIII atom, and one 4-methylmorpholin-4-ium cation. The BiIII atoms are linked by the bridging chloride ligands into linear chains parallel to the c...
Main Author: | |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2012-02-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812001717 |
Summary: | The asymmetric unit of the title complex, {(C5H12NO)[BiCl4]}n, contains two bridging and two cis non-bridging chloride ligands coordinated to a central BiIII atom, and one 4-methylmorpholin-4-ium cation. The BiIII atoms are linked by the bridging chloride ligands into linear chains parallel to the c axis. The chloride ions create a pseudo-octahedral geometry about each BiIII atom. Bifurcated N—H...Cl hydrogen bonds link the cations to the anionic chains. |
---|---|
ISSN: | 1600-5368 |