Changes of Meranti, Padauk, and Merbau Wood Lignin during the ThermoWood Process

• Main Authors: Danica Kačíková, Ivan Kubovský, Milan Gaff, František Kačík
• Format: Article
• Language: English
• Published: MDPI AG 2021-03-01
• Series: Polymers
• Subjects: meranti; padauk; merbau; thermal treatment; wood lignin
• Online Access: https://www.mdpi.com/2073-4360/13/7/993

Thermal modification is an environmentally friendly process in which technological properties of wood are modified using thermal energy without adding chemicals, the result of which is a value-added product. Wood samples of three tropical wood species (meranti, padauk, and merbau) were thermally treated according to the ThermoWood process at various temperatures (160, 180, 210 °C) and changes in isolated lignin were evaluated by nitrobenzene oxidation (NBO), Fourier-transform infrared spectroscopy (FTIR), and size exclusion chromatography (SEC). New data on the lignins of the investigated wood species were obtained, e.g., syringyl to guaiacyl ratio values (S/G) were 1.21, 1.70, and 3.09, and molecular weights were approx. 8600, 4300, and 8300 g·mol⁻¹ for meranti, padauk, and merbau, respectively. Higher temperatures cause a decrease of methoxyls and an increase in C=O groups. Simultaneous degradation and condensation reactions in lignin occur during thermal treatment, the latter prevailing at higher temperatures.