Radical Smiles Rearrangement: An Update

Radical Smiles Rearrangement: An Update

Over the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of t...

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Bibliographic Details
Main Authors: Ingrid Allart-Simon, Stéphane Gérard, Janos Sapi
Format: Article
Language:English
Published: MDPI AG 2016-07-01
Series:Molecules
Subjects:
radical chemistry
Smiles rearrangement
domino reactions
radical cascade
heterocycle
Online Access:http://www.mdpi.com/1420-3049/21/7/878
Description
Summary:Over the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of this approach, especially if it is incorporated into a domino process, for the preparation of polyfunctionalized complex molecules.
ISSN:1420-3049

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