Radical Smiles Rearrangement: An Update

Radical Smiles Rearrangement: An Update

Over the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of t...

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Bibliographic Details
Main Authors: Ingrid Allart-Simon, Stéphane Gérard, Janos Sapi
Format: Article
Language:English
Published: MDPI AG 2016-07-01
Series:Molecules
Subjects:
radical chemistry
Smiles rearrangement
domino reactions
radical cascade
heterocycle
Online Access:http://www.mdpi.com/1420-3049/21/7/878
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spelling doaj-e35dfc26e5424e649b0ac8461e2052a72020-11-24T22:20:41ZengMDPI AGMolecules1420-30492016-07-0121787810.3390/molecules21070878molecules21070878Radical Smiles Rearrangement: An UpdateIngrid Allart-Simon0Stéphane Gérard1Janos Sapi2Institut de Chimie Moléculaire de Reims, UMR CNRS 7312, Université de Reims-Champagne-Ardenne, Faculté de Pharmacie, 51 rue Cognacq-Jay, F-51096 Reims Cedex, FranceInstitut de Chimie Moléculaire de Reims, UMR CNRS 7312, Université de Reims-Champagne-Ardenne, Faculté de Pharmacie, 51 rue Cognacq-Jay, F-51096 Reims Cedex, FranceInstitut de Chimie Moléculaire de Reims, UMR CNRS 7312, Université de Reims-Champagne-Ardenne, Faculté de Pharmacie, 51 rue Cognacq-Jay, F-51096 Reims Cedex, FranceOver the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of this approach, especially if it is incorporated into a domino process, for the preparation of polyfunctionalized complex molecules.http://www.mdpi.com/1420-3049/21/7/878radical chemistrySmiles rearrangementdomino reactionsradical cascadeheterocycle
collection DOAJ
language English
format Article
sources DOAJ
author Ingrid Allart-Simon
Stéphane Gérard
Janos Sapi
spellingShingle Ingrid Allart-Simon
Stéphane Gérard
Janos Sapi
Radical Smiles Rearrangement: An Update
Molecules
radical chemistry
Smiles rearrangement
domino reactions
radical cascade
heterocycle
author_facet Ingrid Allart-Simon
Stéphane Gérard
Janos Sapi
author_sort Ingrid Allart-Simon
title Radical Smiles Rearrangement: An Update
title_short Radical Smiles Rearrangement: An Update
title_full Radical Smiles Rearrangement: An Update
title_fullStr Radical Smiles Rearrangement: An Update
title_full_unstemmed Radical Smiles Rearrangement: An Update
title_sort radical smiles rearrangement: an update
publisher MDPI AG
series Molecules
issn 1420-3049
publishDate 2016-07-01
description Over the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of this approach, especially if it is incorporated into a domino process, for the preparation of polyfunctionalized complex molecules.
topic radical chemistry
Smiles rearrangement
domino reactions
radical cascade
heterocycle
url http://www.mdpi.com/1420-3049/21/7/878
work_keys_str_mv AT ingridallartsimon radicalsmilesrearrangementanupdate
AT stephanegerard radicalsmilesrearrangementanupdate
AT janossapi radicalsmilesrearrangementanupdate
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