Poly[(μ4-biphenyl-2,4′-dicarboxylato-κ5O2:O2′:O4:O4,O4′)zinc]

Poly[(μ4-biphenyl-2,4′-dicarboxylato-κ5O2:O2′:O4:O4,O4′)zinc]

The crystal structure of the polymeric title complex, [Zn(C14H8O4)]n, is composed of layers parallel to (110) formed by linking of Zn–carboxylate chains with biphenyl units of the biphenyl-2,4′-dicarboxylate (bpdc) ligands. The ZnII atom is five-coordinated in a distorted...

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Bibliographic Details
Main Author: Yu-Guang Tian
Format: Article
Language:English
Published: International Union of Crystallography 2012-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812038901
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spelling doaj-e44c9fe9279442b78499f0154b3240162020-11-25T03:34:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-10-016810m1276m127610.1107/S1600536812038901Poly[(μ4-biphenyl-2,4′-dicarboxylato-κ5O2:O2′:O4:O4,O4′)zinc]Yu-Guang TianThe crystal structure of the polymeric title complex, [Zn(C14H8O4)]n, is composed of layers parallel to (110) formed by linking of Zn–carboxylate chains with biphenyl units of the biphenyl-2,4′-dicarboxylate (bpdc) ligands. The ZnII atom is five-coordinated in a distorted square-pyramidal geometry by five O atoms from four bpdc ligands. The dihedral angle between the benzene rings is 52.32 (12)°.http://scripts.iucr.org/cgi-bin/paper?S1600536812038901
collection DOAJ
language English
format Article
sources DOAJ
author Yu-Guang Tian
spellingShingle Yu-Guang Tian
Poly[(μ4-biphenyl-2,4′-dicarboxylato-κ5O2:O2′:O4:O4,O4′)zinc]
Acta Crystallographica Section E
author_facet Yu-Guang Tian
author_sort Yu-Guang Tian
title Poly[(μ4-biphenyl-2,4′-dicarboxylato-κ5O2:O2′:O4:O4,O4′)zinc]
title_short Poly[(μ4-biphenyl-2,4′-dicarboxylato-κ5O2:O2′:O4:O4,O4′)zinc]
title_full Poly[(μ4-biphenyl-2,4′-dicarboxylato-κ5O2:O2′:O4:O4,O4′)zinc]
title_fullStr Poly[(μ4-biphenyl-2,4′-dicarboxylato-κ5O2:O2′:O4:O4,O4′)zinc]
title_full_unstemmed Poly[(μ4-biphenyl-2,4′-dicarboxylato-κ5O2:O2′:O4:O4,O4′)zinc]
title_sort poly[(μ4-biphenyl-2,4′-dicarboxylato-κ5o2:o2′:o4:o4,o4′)zinc]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-10-01
description The crystal structure of the polymeric title complex, [Zn(C14H8O4)]n, is composed of layers parallel to (110) formed by linking of Zn–carboxylate chains with biphenyl units of the biphenyl-2,4′-dicarboxylate (bpdc) ligands. The ZnII atom is five-coordinated in a distorted square-pyramidal geometry by five O atoms from four bpdc ligands. The dihedral angle between the benzene rings is 52.32 (12)°.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812038901
work_keys_str_mv AT yuguangtian polyamp9564biphenyl24amp8242dicarboxylatoamp9545o2o2amp8242o4o4o4amp8242zinc
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