2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate
The organic cation of the title salt, C17H12N4O2+·2Cl−·H2O, is nearly planar, the dihedral angle between two pyridine rings being 2.53 (16)° and that between the pyridinum and furan rings being 4.17 (19)°. Molecules are linked via N&a...
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International Union of Crystallography
2009-02-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809001160 |
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doaj-e50d8e7de2944fbf9d9060b3bb85d6dc2020-11-25T00:14:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652o341o34110.1107/S16005368090011602-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrateZhu TaoSai-Feng XueQian-Jiang ZhuYun-Qian ZhangMing-Hua ChenThe organic cation of the title salt, C17H12N4O2+·2Cl−·H2O, is nearly planar, the dihedral angle between two pyridine rings being 2.53 (16)° and that between the pyridinum and furan rings being 4.17 (19)°. Molecules are linked via N—H...O, N—H...Cl and O—H...Cl hydrogen bonds, forming a three-dimensional framework and π–π stacking interactions help to stabilize the crystal structure [the imidazole–pyridine and imidazole–benzene centroid–centroid distances are 3.501 (3) and 3.674 (3) Å; respectively].http://scripts.iucr.org/cgi-bin/paper?S1600536809001160 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Zhu Tao Sai-Feng Xue Qian-Jiang Zhu Yun-Qian Zhang Ming-Hua Chen |
spellingShingle |
Zhu Tao Sai-Feng Xue Qian-Jiang Zhu Yun-Qian Zhang Ming-Hua Chen 2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate Acta Crystallographica Section E |
author_facet |
Zhu Tao Sai-Feng Xue Qian-Jiang Zhu Yun-Qian Zhang Ming-Hua Chen |
author_sort |
Zhu Tao |
title |
2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
title_short |
2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
title_full |
2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
title_fullStr |
2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
title_full_unstemmed |
2-(2-Furyl)-1H-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
title_sort |
2-(2-furyl)-1h-imidazo[4,5-f][1,10]phenanthroline-3,7-diium dichloride monohydrate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2009-02-01 |
description |
The organic cation of the title salt, C17H12N4O2+·2Cl−·H2O, is nearly planar, the dihedral angle between two pyridine rings being 2.53 (16)° and that between the pyridinum and furan rings being 4.17 (19)°. Molecules are linked via N—H...O, N—H...Cl and O—H...Cl hydrogen bonds, forming a three-dimensional framework and π–π stacking interactions help to stabilize the crystal structure [the imidazole–pyridine and imidazole–benzene centroid–centroid distances are 3.501 (3) and 3.674 (3) Å; respectively]. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809001160 |
work_keys_str_mv |
AT zhutao 22furyl1himidazo45f110phenanthroline37diiumdichloridemonohydrate AT saifengxue 22furyl1himidazo45f110phenanthroline37diiumdichloridemonohydrate AT qianjiangzhu 22furyl1himidazo45f110phenanthroline37diiumdichloridemonohydrate AT yunqianzhang 22furyl1himidazo45f110phenanthroline37diiumdichloridemonohydrate AT minghuachen 22furyl1himidazo45f110phenanthroline37diiumdichloridemonohydrate |
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