catena-Poly[[[aqua(di-2-pyridylamine-κ2N2,N2′)manganese(II)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ3O1,O1′:O3] methanol monosolvate monohydrate]

catena-Poly[[[aqua(di-2-pyridylamine-κ2N2,N2′)manganese(II)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ3O1,O1′:O3] methanol monosolvate monohydrate]

In the title coordination polymer, {[FeMn(C5H5)(C13H7O4)(C10H9N3)(H2O)]·CH3OH·H2O}n, the MnII ion has a distorted octahedral coordination geometry and is ligated by two N atoms from two di-2-pyridylamine molecules, three O atoms from two 5-ferrocenylbenzene-1,3-dicarboxylat...

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Bibliographic Details
Main Authors: Wei Liu, Gang Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811022781
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spelling doaj-e55e270e6d5f45e9a3cc1b22a81fa8522020-11-25T01:27:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m989m99010.1107/S1600536811022781catena-Poly[[[aqua(di-2-pyridylamine-κ2N2,N2′)manganese(II)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ3O1,O1′:O3] methanol monosolvate monohydrate]Wei LiuGang ZhangIn the title coordination polymer, {[FeMn(C5H5)(C13H7O4)(C10H9N3)(H2O)]·CH3OH·H2O}n, the MnII ion has a distorted octahedral coordination geometry and is ligated by two N atoms from two di-2-pyridylamine molecules, three O atoms from two 5-ferrocenylbenzene-1,3-dicarboxylate anions and one O atom from a coordinated water molecule. The Mn—O distances range from 2.151 (2) to 2.5093 (19) Å, while the Mn—N distances are 2.226 (2) and 2.248 (2) Å. Each 5-ferrocenylbenzene-1,5-dicarboxylate anion links to two MnII ions, resulting in a chain along the b axis. A three-dimensional network of N—H...O and O—H...O hydrogen bonds helps to stabilize the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536811022781
collection DOAJ
language English
format Article
sources DOAJ
author Wei Liu
Gang Zhang
spellingShingle Wei Liu
Gang Zhang
catena-Poly[[[aqua(di-2-pyridylamine-κ2N2,N2′)manganese(II)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ3O1,O1′:O3] methanol monosolvate monohydrate]
Acta Crystallographica Section E
author_facet Wei Liu
Gang Zhang
author_sort Wei Liu
title catena-Poly[[[aqua(di-2-pyridylamine-κ2N2,N2′)manganese(II)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ3O1,O1′:O3] methanol monosolvate monohydrate]
title_short catena-Poly[[[aqua(di-2-pyridylamine-κ2N2,N2′)manganese(II)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ3O1,O1′:O3] methanol monosolvate monohydrate]
title_full catena-Poly[[[aqua(di-2-pyridylamine-κ2N2,N2′)manganese(II)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ3O1,O1′:O3] methanol monosolvate monohydrate]
title_fullStr catena-Poly[[[aqua(di-2-pyridylamine-κ2N2,N2′)manganese(II)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ3O1,O1′:O3] methanol monosolvate monohydrate]
title_full_unstemmed catena-Poly[[[aqua(di-2-pyridylamine-κ2N2,N2′)manganese(II)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ3O1,O1′:O3] methanol monosolvate monohydrate]
title_sort catena-poly[[[aqua(di-2-pyridylamine-κ2n2,n2′)manganese(ii)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ3o1,o1′:o3] methanol monosolvate monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-07-01
description In the title coordination polymer, {[FeMn(C5H5)(C13H7O4)(C10H9N3)(H2O)]·CH3OH·H2O}n, the MnII ion has a distorted octahedral coordination geometry and is ligated by two N atoms from two di-2-pyridylamine molecules, three O atoms from two 5-ferrocenylbenzene-1,3-dicarboxylate anions and one O atom from a coordinated water molecule. The Mn—O distances range from 2.151 (2) to 2.5093 (19) Å, while the Mn—N distances are 2.226 (2) and 2.248 (2) Å. Each 5-ferrocenylbenzene-1,5-dicarboxylate anion links to two MnII ions, resulting in a chain along the b axis. A three-dimensional network of N—H...O and O—H...O hydrogen bonds helps to stabilize the crystal packing.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811022781
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AT gangzhang catenapolyaquadi2pyridylamineamp9542n2n2amp8242manganeseiiamp9565ferrocenylbenzene13dicarboxylatoamp9543o1o1amp8242o3methanolmonosolvatemonohydrate
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