Giant coercivity and high magnetic blocking temperatures for N2 3− radical-bridged dilanthanide complexes upon ligand dissociation

Single-molecule magnets typically only retain information in the presence of an applied magnetic field and at very low temperatures. Here, Demir, Long and co-workers design N2 3– radical-bridged dilanthanide complexes that exhibit giant coercivities and 100-s magnetic blocking temperatures of up to...

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Main Authors:	Selvan Demir, Miguel I. Gonzalez, Lucy E. Darago, William J. Evans, Jeffrey R. Long
Format:	Article
Language:	English
Published:	Nature Publishing Group 2017-12-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-017-01553-w

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spelling	doaj-e578473e914c4403a1b62d9371b6123f2021-05-11T07:12:42ZengNature Publishing GroupNature Communications2041-17232017-12-01811910.1038/s41467-017-01553-wGiant coercivity and high magnetic blocking temperatures for N2 3− radical-bridged dilanthanide complexes upon ligand dissociationSelvan Demir0Miguel I. Gonzalez1Lucy E. Darago2William J. Evans3Jeffrey R. Long4Department of Chemistry, University of CaliforniaDepartment of Chemistry, University of CaliforniaDepartment of Chemistry, University of CaliforniaDepartment of Chemistry, University of CaliforniaDepartment of Chemistry, University of CaliforniaSingle-molecule magnets typically only retain information in the presence of an applied magnetic field and at very low temperatures. Here, Demir, Long and co-workers design N2 3– radical-bridged dilanthanide complexes that exhibit giant coercivities and 100-s magnetic blocking temperatures of up to 20 K.https://doi.org/10.1038/s41467-017-01553-w
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Selvan Demir Miguel I. Gonzalez Lucy E. Darago William J. Evans Jeffrey R. Long
spellingShingle	Selvan Demir Miguel I. Gonzalez Lucy E. Darago William J. Evans Jeffrey R. Long Giant coercivity and high magnetic blocking temperatures for N2 3− radical-bridged dilanthanide complexes upon ligand dissociation Nature Communications
author_facet	Selvan Demir Miguel I. Gonzalez Lucy E. Darago William J. Evans Jeffrey R. Long
author_sort	Selvan Demir
title	Giant coercivity and high magnetic blocking temperatures for N2 3− radical-bridged dilanthanide complexes upon ligand dissociation
title_short	Giant coercivity and high magnetic blocking temperatures for N2 3− radical-bridged dilanthanide complexes upon ligand dissociation
title_full	Giant coercivity and high magnetic blocking temperatures for N2 3− radical-bridged dilanthanide complexes upon ligand dissociation
title_fullStr	Giant coercivity and high magnetic blocking temperatures for N2 3− radical-bridged dilanthanide complexes upon ligand dissociation
title_full_unstemmed	Giant coercivity and high magnetic blocking temperatures for N2 3− radical-bridged dilanthanide complexes upon ligand dissociation
title_sort	giant coercivity and high magnetic blocking temperatures for n2 3− radical-bridged dilanthanide complexes upon ligand dissociation
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2017-12-01
description	Single-molecule magnets typically only retain information in the presence of an applied magnetic field and at very low temperatures. Here, Demir, Long and co-workers design N2 3– radical-bridged dilanthanide complexes that exhibit giant coercivities and 100-s magnetic blocking temperatures of up to 20 K.
url	https://doi.org/10.1038/s41467-017-01553-w
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Giant coercivity and high magnetic blocking temperatures for N2 3− radical-bridged dilanthanide complexes upon ligand dissociation

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