Functionalization and Evaluation of Inorganic Adsorbents for the Removal of Cadmium in Wastewater

• Main Authors: Ana Lucía Campaña, Amaimen Guillén, Ricardo Rivas, Veronica Akle, Juan C. Cruz, Johann F. Osma
• Format: Article
• Language: English
• Published: MDPI AG 2021-07-01
• Series: Molecules
• Subjects: wastewater; cadmium; magnetite nanoparticles; alumina; functionalization
• Online Access: https://www.mdpi.com/1420-3049/26/14/4150

This study presents the feasibility of using various functionalized substrates, Fe₃O₄ nanoparticles (NPs) and Al₂O₃ spheres, for the removal of Cd from aqueous solution. To improve the materials’ affinity to Cd, we explored four different surface modifications, namely (3-Aminopropyl) triethoxysilane (APTES), L-Cysteine (Cys) and 3-(triethoxysilyl) propylsuccinic anhydride (CAS). Particles were characterized by FTIR, FIB-SEM and DLS and studied for their ability to remove metal ions. Modified NPs with APTES proved to be effective for Cd removal with efficiencies of up to 94%, and retention ratios up to 0.49 mg of Cd per g of NPs. Batch adsorption experiments investigated the influence of pH, contact time, and adsorbent dose on Cd adsorption. Additionally, the recyclability of the adsorbent and its potential phytotoxicity and animal toxicity effects were explored. The Langmuir, Freundlich, pseudo-first-order and pseudo-second-order models were applied to describe the behavior of the Cd adsorption processes. The adsorption and desorption results showed that Fe₃O₄ NPs modified with APTES are promising low-cost platforms with low phytotoxicity for highly efficient heavy metal removal in wastewater.