Flue Gas Desulphurization in Circulating Fluidized Beds

Sulphur dioxide (SO<sub>2</sub>) is mostly emitted from coal-fueled power plants, from waste incineration, from sulphuric acid manufacturing, from clay brick plants and from treating nonferrous metals. The emission of SO<sub>2</sub> needs to be abated. Both wet scrubbing (abs...

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Main Authors: Yimin Deng, Renaud Ansart, Jan Baeyens, Huili Zhang
Format: Article
Language:English
Published: MDPI AG 2019-10-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/12/20/3908
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spelling doaj-e59edd67e6e4448597900b0f46983e392020-11-24T21:56:15ZengMDPI AGEnergies1996-10732019-10-011220390810.3390/en12203908en12203908Flue Gas Desulphurization in Circulating Fluidized BedsYimin Deng0Renaud Ansart1Jan Baeyens2Huili Zhang3Laboratoire de Génie Chimique, Université de Toulouse, CNRS, INPT, UPS, 31432 Cedex 4 Toulouse, FranceLaboratoire de Génie Chimique, Université de Toulouse, CNRS, INPT, UPS, 31432 Cedex 4 Toulouse, FranceBeijing Advanced Innovation Centre of Soft Matter and Engineering, Beijing University of Chemical Technology, Beijing 100029, ChinaSchool of Life Science and Technology, Beijing University of Chemical Technology, Beijing 100029, ChinaSulphur dioxide (SO<sub>2</sub>) is mostly emitted from coal-fueled power plants, from waste incineration, from sulphuric acid manufacturing, from clay brick plants and from treating nonferrous metals. The emission of SO<sub>2</sub> needs to be abated. Both wet scrubbing (absorption) and dry or semi-dry (reaction) systems are used. In the dry process, both bubbling and circulating fluidized beds (BFB, CFB) can be used as contactor. Experimental results demonstrate a SO<sub>2</sub>-removal efficiency in excess of 94% in a CFB application. A general model of the heterogeneous reaction is proposed, combining the external diffusion of SO<sub>2</sub> across the gas film, the internal diffusion of SO<sub>2</sub> in the porous particles and the reaction as such (irreversible, 1st order). For the reaction of SO<sub>2</sub> with a fine particulate reactant, the reaction rate constant and the relevant contact time are the dominant parameters. Application of the model equations reveals that the circulating fluidized bed is the most appropriate technique, where the high solid to gas ratio guarantees a high conversion in a short reaction time. For the CFB operation, the required gas contact time in a CFB at given superficial gas velocities and solids circulation rates will determine the SO<sub>2</sub> removal rate.https://www.mdpi.com/1996-1073/12/20/3908so<sub>2</sub> abatementdry or semi-dry reactioncalcium oxidemodelefficiency
collection DOAJ
language English
format Article
sources DOAJ
author Yimin Deng
Renaud Ansart
Jan Baeyens
Huili Zhang
spellingShingle Yimin Deng
Renaud Ansart
Jan Baeyens
Huili Zhang
Flue Gas Desulphurization in Circulating Fluidized Beds
Energies
so<sub>2</sub> abatement
dry or semi-dry reaction
calcium oxide
model
efficiency
author_facet Yimin Deng
Renaud Ansart
Jan Baeyens
Huili Zhang
author_sort Yimin Deng
title Flue Gas Desulphurization in Circulating Fluidized Beds
title_short Flue Gas Desulphurization in Circulating Fluidized Beds
title_full Flue Gas Desulphurization in Circulating Fluidized Beds
title_fullStr Flue Gas Desulphurization in Circulating Fluidized Beds
title_full_unstemmed Flue Gas Desulphurization in Circulating Fluidized Beds
title_sort flue gas desulphurization in circulating fluidized beds
publisher MDPI AG
series Energies
issn 1996-1073
publishDate 2019-10-01
description Sulphur dioxide (SO<sub>2</sub>) is mostly emitted from coal-fueled power plants, from waste incineration, from sulphuric acid manufacturing, from clay brick plants and from treating nonferrous metals. The emission of SO<sub>2</sub> needs to be abated. Both wet scrubbing (absorption) and dry or semi-dry (reaction) systems are used. In the dry process, both bubbling and circulating fluidized beds (BFB, CFB) can be used as contactor. Experimental results demonstrate a SO<sub>2</sub>-removal efficiency in excess of 94% in a CFB application. A general model of the heterogeneous reaction is proposed, combining the external diffusion of SO<sub>2</sub> across the gas film, the internal diffusion of SO<sub>2</sub> in the porous particles and the reaction as such (irreversible, 1st order). For the reaction of SO<sub>2</sub> with a fine particulate reactant, the reaction rate constant and the relevant contact time are the dominant parameters. Application of the model equations reveals that the circulating fluidized bed is the most appropriate technique, where the high solid to gas ratio guarantees a high conversion in a short reaction time. For the CFB operation, the required gas contact time in a CFB at given superficial gas velocities and solids circulation rates will determine the SO<sub>2</sub> removal rate.
topic so<sub>2</sub> abatement
dry or semi-dry reaction
calcium oxide
model
efficiency
url https://www.mdpi.com/1996-1073/12/20/3908
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AT huilizhang fluegasdesulphurizationincirculatingfluidizedbeds
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