Electrochemical reduction of acetonitrile to ethylamine

Industrial synthesis of primary amine often features poor selectivity because of the formation of secondary and tertiary amine byproducts. Here, the authors report an electrocatalytic route to ethylamine through selective electroreduction of acetonitrile at ambient temperature and pressure.

Bibliographic Details
Main Authors: Rong Xia, Dong Tian, Shyam Kattel, Bjorn Hasa, Haeun Shin, Xinbin Ma, Jingguang G. Chen, Feng Jiao
Format: Article
Language:English
Published: Nature Publishing Group 2021-03-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-021-22291-0
Description
Summary:Industrial synthesis of primary amine often features poor selectivity because of the formation of secondary and tertiary amine byproducts. Here, the authors report an electrocatalytic route to ethylamine through selective electroreduction of acetonitrile at ambient temperature and pressure.
ISSN:2041-1723