Adsorption Synthesis of Iron Oxide-Supported Gold Catalyst under Self-Generated Alkaline Conditions for Efficient Elimination of Carbon Monoxide
Goethite- and hematite-supported highly dispersed gold catalysts for carbon monoxide oxidation were synthesized by gold precursor adsorption onto the support materials in self-generated alkaline solutions. The support materials were prepared by reacting iron nitrate with excess sodium hydroxide. The...
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doaj-e6239f76c7444792988b96789d5400c62020-11-25T01:13:46ZengMDPI AGCatalysts2073-43442018-08-018935710.3390/catal8090357catal8090357Adsorption Synthesis of Iron Oxide-Supported Gold Catalyst under Self-Generated Alkaline Conditions for Efficient Elimination of Carbon MonoxideFeng Pan0Weidong Zhang1Yuxiao Ye2Yixuan Huang3Yanzhe Xu4Yufeng Yuan5Feng Wu6Jinjun Li7School of Resources and Environmental Sciences, Wuhan University, Wuhan 430079, ChinaSchool of Resources and Environmental Sciences, Wuhan University, Wuhan 430079, ChinaSchool of Resources and Environmental Sciences, Wuhan University, Wuhan 430079, ChinaSchool of Resources and Environmental Sciences, Wuhan University, Wuhan 430079, ChinaSchool of Resources and Environmental Sciences, Wuhan University, Wuhan 430079, ChinaSchool of Resources and Environmental Sciences, Wuhan University, Wuhan 430079, ChinaSchool of Resources and Environmental Sciences, Wuhan University, Wuhan 430079, ChinaSchool of Resources and Environmental Sciences, Wuhan University, Wuhan 430079, ChinaGoethite- and hematite-supported highly dispersed gold catalysts for carbon monoxide oxidation were synthesized by gold precursor adsorption onto the support materials in self-generated alkaline solutions. The support materials were prepared by reacting iron nitrate with excess sodium hydroxide. The residual minor alkali incorporated into the support could provide suitable alkaline conditions at approximately pH 8 for the hydrolysis of tetrachloroaurate anions and the subsequent adsorption process. Gold species underwent autoreduction to achieve activation during the synthesis. An increase in pH or temperature to 80 °C decreased the gold loading of the catalysts. The optimal catalysts could achieve complete oxidation of carbon monoxide at −20 °C.http://www.mdpi.com/2073-4344/8/9/357adsorptioniron oxidegoldcarbon monoxidecatalytic oxidation |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Feng Pan Weidong Zhang Yuxiao Ye Yixuan Huang Yanzhe Xu Yufeng Yuan Feng Wu Jinjun Li |
spellingShingle |
Feng Pan Weidong Zhang Yuxiao Ye Yixuan Huang Yanzhe Xu Yufeng Yuan Feng Wu Jinjun Li Adsorption Synthesis of Iron Oxide-Supported Gold Catalyst under Self-Generated Alkaline Conditions for Efficient Elimination of Carbon Monoxide Catalysts adsorption iron oxide gold carbon monoxide catalytic oxidation |
author_facet |
Feng Pan Weidong Zhang Yuxiao Ye Yixuan Huang Yanzhe Xu Yufeng Yuan Feng Wu Jinjun Li |
author_sort |
Feng Pan |
title |
Adsorption Synthesis of Iron Oxide-Supported Gold Catalyst under Self-Generated Alkaline Conditions for Efficient Elimination of Carbon Monoxide |
title_short |
Adsorption Synthesis of Iron Oxide-Supported Gold Catalyst under Self-Generated Alkaline Conditions for Efficient Elimination of Carbon Monoxide |
title_full |
Adsorption Synthesis of Iron Oxide-Supported Gold Catalyst under Self-Generated Alkaline Conditions for Efficient Elimination of Carbon Monoxide |
title_fullStr |
Adsorption Synthesis of Iron Oxide-Supported Gold Catalyst under Self-Generated Alkaline Conditions for Efficient Elimination of Carbon Monoxide |
title_full_unstemmed |
Adsorption Synthesis of Iron Oxide-Supported Gold Catalyst under Self-Generated Alkaline Conditions for Efficient Elimination of Carbon Monoxide |
title_sort |
adsorption synthesis of iron oxide-supported gold catalyst under self-generated alkaline conditions for efficient elimination of carbon monoxide |
publisher |
MDPI AG |
series |
Catalysts |
issn |
2073-4344 |
publishDate |
2018-08-01 |
description |
Goethite- and hematite-supported highly dispersed gold catalysts for carbon monoxide oxidation were synthesized by gold precursor adsorption onto the support materials in self-generated alkaline solutions. The support materials were prepared by reacting iron nitrate with excess sodium hydroxide. The residual minor alkali incorporated into the support could provide suitable alkaline conditions at approximately pH 8 for the hydrolysis of tetrachloroaurate anions and the subsequent adsorption process. Gold species underwent autoreduction to achieve activation during the synthesis. An increase in pH or temperature to 80 °C decreased the gold loading of the catalysts. The optimal catalysts could achieve complete oxidation of carbon monoxide at −20 °C. |
topic |
adsorption iron oxide gold carbon monoxide catalytic oxidation |
url |
http://www.mdpi.com/2073-4344/8/9/357 |
work_keys_str_mv |
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