Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}

Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}

In the title centrosymmetric binuclear complex, [Cd2(NO2)4(C11H9N5)2], the unique CdII ion is in a distorted dodecahedral CdN3O5 coordination environment. The two inversion-related CdII ions are separated by 3.9920 (6) Å and are bridged by two O atoms from tw...

Full description

Bibliographic Details
Main Authors: Ting Ting Sun, Lin Meng, Jing Min Shi
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809039841
Description
Summary:In the title centrosymmetric binuclear complex, [Cd2(NO2)4(C11H9N5)2], the unique CdII ion is in a distorted dodecahedral CdN3O5 coordination environment. The two inversion-related CdII ions are separated by 3.9920 (6) Å and are bridged by two O atoms from two nitrite ligands. There are two types of π–π stacking interactions involving symmetry-related pyrazole rings, with centroid–centroid distances of 3.445 (2) and 3.431 (2) Å.
ISSN:1600-5368

Similar Items