Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}

Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}

In the title centrosymmetric binuclear complex, [Cd2(NO2)4(C11H9N5)2], the unique CdII ion is in a distorted dodecahedral CdN3O5 coordination environment. The two inversion-related CdII ions are separated by 3.9920 (6) Å and are bridged by two O atoms from tw...

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Main Authors: Ting Ting Sun, Lin Meng, Jing Min Shi
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809039841
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spelling doaj-e71bd59c27b84db98ed0a6c2b132052a2020-11-24T21:32:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1318m131810.1107/S1600536809039841Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}Ting Ting SunLin MengJing Min ShiIn the title centrosymmetric binuclear complex, [Cd2(NO2)4(C11H9N5)2], the unique CdII ion is in a distorted dodecahedral CdN3O5 coordination environment. The two inversion-related CdII ions are separated by 3.9920 (6) Å and are bridged by two O atoms from two nitrite ligands. There are two types of π–π stacking interactions involving symmetry-related pyrazole rings, with centroid–centroid distances of 3.445 (2) and 3.431 (2) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536809039841
collection DOAJ
language English
format Article
sources DOAJ
author Ting Ting Sun
Lin Meng
Jing Min Shi
spellingShingle Ting Ting Sun
Lin Meng
Jing Min Shi
Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}
Acta Crystallographica Section E
author_facet Ting Ting Sun
Lin Meng
Jing Min Shi
author_sort Ting Ting Sun
title Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}
title_short Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}
title_full Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}
title_fullStr Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}
title_full_unstemmed Di-μ-nitrito-κ3O:O,O′;κ3O,O′:O-bis{[2,6-bis(pyrazol-1-yl-κN2)pyridine-κN](nitrito-κ2O,O′)cadmium(II)}
title_sort di-μ-nitrito-κ3o:o,o′;κ3o,o′:o-bis{[2,6-bis(pyrazol-1-yl-κn2)pyridine-κn](nitrito-κ2o,o′)cadmium(ii)}
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-11-01
description In the title centrosymmetric binuclear complex, [Cd2(NO2)4(C11H9N5)2], the unique CdII ion is in a distorted dodecahedral CdN3O5 coordination environment. The two inversion-related CdII ions are separated by 3.9920 (6) Å and are bridged by two O atoms from two nitrite ligands. There are two types of π–π stacking interactions involving symmetry-related pyrazole rings, with centroid–centroid distances of 3.445 (2) and 3.431 (2) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809039841
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AT linmeng diamp956nitritoamp9543oooamp8242amp9543ooamp8242obis26bispyrazol1ylamp954n2pyridineamp954nnitritoamp9542ooamp8242cadmiumii
AT jingminshi diamp956nitritoamp9543oooamp8242amp9543ooamp8242obis26bispyrazol1ylamp954n2pyridineamp954nnitritoamp9542ooamp8242cadmiumii
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