Poly[bis(μ2-pyrimidine-κ2N:N′)bis(selenocyanato-κN)zinc]

Poly[bis(μ2-pyrimidine-κ2N:N′)bis(selenocyanato-κN)zinc]

The asymmetric unit of the title compound, [Zn(NCSe)2(C4H4N2)2]n, consists of one Zn2+ cation located on a special position with site symmetry 2/m, one selenocyanate anion on a mirror plane and one pyrimidine ligand on a twofold rotation axis. The zinc cation is coordinated by six N atoms of four py...

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Main Authors: Jan Boeckmann, Thorben Reinert, Christian Näther
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811023129
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spelling doaj-e76388e68ecd4c438a8e501e5001d5172020-11-25T01:11:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m948m94810.1107/S1600536811023129Poly[bis(μ2-pyrimidine-κ2N:N′)bis(selenocyanato-κN)zinc]Jan BoeckmannThorben ReinertChristian NätherThe asymmetric unit of the title compound, [Zn(NCSe)2(C4H4N2)2]n, consists of one Zn2+ cation located on a special position with site symmetry 2/m, one selenocyanate anion on a mirror plane and one pyrimidine ligand on a twofold rotation axis. The zinc cation is coordinated by six N atoms of four pyrimidine ligands and two N-bonded selenocyanate anions in mutually trans orientations within a slightly distorted octahedral coordination environment. The Zn atoms are μ-1,3-bridged via the pyrimidine ligands into a polymeric layer extending parallel to (100).http://scripts.iucr.org/cgi-bin/paper?S1600536811023129
collection DOAJ
language English
format Article
sources DOAJ
author Jan Boeckmann
Thorben Reinert
Christian Näther
spellingShingle Jan Boeckmann
Thorben Reinert
Christian Näther
Poly[bis(μ2-pyrimidine-κ2N:N′)bis(selenocyanato-κN)zinc]
Acta Crystallographica Section E
author_facet Jan Boeckmann
Thorben Reinert
Christian Näther
author_sort Jan Boeckmann
title Poly[bis(μ2-pyrimidine-κ2N:N′)bis(selenocyanato-κN)zinc]
title_short Poly[bis(μ2-pyrimidine-κ2N:N′)bis(selenocyanato-κN)zinc]
title_full Poly[bis(μ2-pyrimidine-κ2N:N′)bis(selenocyanato-κN)zinc]
title_fullStr Poly[bis(μ2-pyrimidine-κ2N:N′)bis(selenocyanato-κN)zinc]
title_full_unstemmed Poly[bis(μ2-pyrimidine-κ2N:N′)bis(selenocyanato-κN)zinc]
title_sort poly[bis(μ2-pyrimidine-κ2n:n′)bis(selenocyanato-κn)zinc]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-07-01
description The asymmetric unit of the title compound, [Zn(NCSe)2(C4H4N2)2]n, consists of one Zn2+ cation located on a special position with site symmetry 2/m, one selenocyanate anion on a mirror plane and one pyrimidine ligand on a twofold rotation axis. The zinc cation is coordinated by six N atoms of four pyrimidine ligands and two N-bonded selenocyanate anions in mutually trans orientations within a slightly distorted octahedral coordination environment. The Zn atoms are μ-1,3-bridged via the pyrimidine ligands into a polymeric layer extending parallel to (100).
url http://scripts.iucr.org/cgi-bin/paper?S1600536811023129
work_keys_str_mv AT janboeckmann polybisamp9562pyrimidineamp9542nnamp8242bisselenocyanatoamp954nzinc
AT thorbenreinert polybisamp9562pyrimidineamp9542nnamp8242bisselenocyanatoamp954nzinc
AT christiannamp228ther polybisamp9562pyrimidineamp9542nnamp8242bisselenocyanatoamp954nzinc
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