Valorization of Waste Tires by Pyrolysis and Activation Processes

• Main Authors: Reyna Berenice González-González, Nadia Ruiz-Gómez, Gloria Gea, Matias Vazquez-Pinon, Sergio O. Martinez-Chapa, Porfirio Caballero, Alberto Mendoza
• Format: Article
• Language: English
• Published: MDPI AG 2021-07-01
• Series: Applied Sciences
• Subjects: pyrolysis; chemical activation; physical activation; waste tires
• Online Access: https://www.mdpi.com/2076-3417/11/14/6342

The problems related to the increase in the generation of discarded tires demonstrate the need for profitable, efficient, cost-effective, and sustainable processes for their waste management. In particular, the valorization of pyrolytic solids for energy storage applications is of interest. In this study, four processes were performed: (1) pyrolysis; (2) chemical activation and pyrolysis; (3) pyrolysis and physical activation; and (4) chemical activation, pyrolysis, and physical activation. The process consisting of chemical activation, pyrolysis, and physical activation yielded 52% solid material with the highest electrical conductivity (2.43 Ω^–1 cm^–1) and a surface area of 339 m²/g with an average pore size of 3.6 nm. In addition, it was found that pore size had a greater effect on the conductivity than surface area. Liquid and gas fraction compositions were modified by the presence of chemical activation: aromatization reactions were favored, and limonene was not observed in the liquid fraction, while an increase on the CH₄ concentration caused an increment in the heating value of the gas fraction. It was demonstrated that chemical and physical activation enhance the properties of the pyrolytic solid product derived from waste tires that make it suitable for the partial substitution of materials for electric energy storage applications.