A Novel Bifunctional Self‐Stabilized Strategy Enabling 4.6 V LiCoO2 with Excellent Long‐Term Cyclability and High‐Rate Capability
Abstract Although the theoretical specific capacity of LiCoO2 is as high as 274 mAh g−1, the superior electrochemical performances of LiCoO2 can be barely achieved due to the issues of severe structure destruction and LiCoO2/electrolyte interface side reactions when the upper cutoff voltage exceeds...
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doaj-e797df96e35a4ab2952b9e1a2a0f0d522020-11-25T01:26:22ZengWileyAdvanced Science2198-38442019-06-01612n/an/a10.1002/advs.201900355A Novel Bifunctional Self‐Stabilized Strategy Enabling 4.6 V LiCoO2 with Excellent Long‐Term Cyclability and High‐Rate CapabilityLonglong Wang0Jun Ma1Chen Wang2Xinrun Yu3Ru Liu4Feng Jiang5Xingwei Sun6Aobing Du7Xinhong Zhou8Guanglei Cui9Qingdao Industrial Energy Storage Research Institute Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences Qingdao 266101 P. R. ChinaQingdao Industrial Energy Storage Research Institute Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences Qingdao 266101 P. R. ChinaQingdao Industrial Energy Storage Research Institute Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences Qingdao 266101 P. R. ChinaCollege of Materials Science and Engineering Qingdao University Qingdao 266071 P. R. ChinaQingdao Industrial Energy Storage Research Institute Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences Qingdao 266101 P. R. ChinaCollege of Chemistry and Molecular Engineering Qingdao University of Science & Technology Qingdao 266042 P. R. ChinaCollege of Chemistry and Molecular Engineering Qingdao University of Science & Technology Qingdao 266042 P. R. ChinaQingdao Industrial Energy Storage Research Institute Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences Qingdao 266101 P. R. ChinaCollege of Chemistry and Molecular Engineering Qingdao University of Science & Technology Qingdao 266042 P. R. ChinaQingdao Industrial Energy Storage Research Institute Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences Qingdao 266101 P. R. ChinaAbstract Although the theoretical specific capacity of LiCoO2 is as high as 274 mAh g−1, the superior electrochemical performances of LiCoO2 can be barely achieved due to the issues of severe structure destruction and LiCoO2/electrolyte interface side reactions when the upper cutoff voltage exceeds 4.5 V. Here, a bifunctional self‐stabilized strategy involving Al+Ti bulk codoping and gradient surface Mg doping is first proposed to synchronously enhance the high‐voltage (4.6 V) performances of LiCoO2. The comodified LiCoO2 (CMLCO) shows an initial discharge capacity of 224.9 mAh g−1 and 78% capacity retention after 200 cycles between 3.0 and 4.6 V. Excitingly, the CMLCO also exhibits a specific capacity of up to 142 mAh g−1 even at 10 C. Moreover, the long‐term cyclability of CMLCO/mesocarbon microbeads full cells is also enhanced significantly even at high temperature of 60 °C. The synergistic effects of this bifunctional self‐stabilized strategy on structural reversibility and interfacial stability are demonstrated by investigating the phase transitions and interface characteristics of cycled LiCoO2. This work will be a milestone breakthrough in the development of high‐voltage LiCoO2. It will also present an instructive contribution for resolving the big structural and interfacial challenges in other high‐energy‐density rechargeable batteries.https://doi.org/10.1002/advs.201900355energy storagehigh energy densityhigh voltageLiCoO2 cathodestructure/interface stability |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Longlong Wang Jun Ma Chen Wang Xinrun Yu Ru Liu Feng Jiang Xingwei Sun Aobing Du Xinhong Zhou Guanglei Cui |
spellingShingle |
Longlong Wang Jun Ma Chen Wang Xinrun Yu Ru Liu Feng Jiang Xingwei Sun Aobing Du Xinhong Zhou Guanglei Cui A Novel Bifunctional Self‐Stabilized Strategy Enabling 4.6 V LiCoO2 with Excellent Long‐Term Cyclability and High‐Rate Capability Advanced Science energy storage high energy density high voltage LiCoO2 cathode structure/interface stability |
author_facet |
Longlong Wang Jun Ma Chen Wang Xinrun Yu Ru Liu Feng Jiang Xingwei Sun Aobing Du Xinhong Zhou Guanglei Cui |
author_sort |
Longlong Wang |
title |
A Novel Bifunctional Self‐Stabilized Strategy Enabling 4.6 V LiCoO2 with Excellent Long‐Term Cyclability and High‐Rate Capability |
title_short |
A Novel Bifunctional Self‐Stabilized Strategy Enabling 4.6 V LiCoO2 with Excellent Long‐Term Cyclability and High‐Rate Capability |
title_full |
A Novel Bifunctional Self‐Stabilized Strategy Enabling 4.6 V LiCoO2 with Excellent Long‐Term Cyclability and High‐Rate Capability |
title_fullStr |
A Novel Bifunctional Self‐Stabilized Strategy Enabling 4.6 V LiCoO2 with Excellent Long‐Term Cyclability and High‐Rate Capability |
title_full_unstemmed |
A Novel Bifunctional Self‐Stabilized Strategy Enabling 4.6 V LiCoO2 with Excellent Long‐Term Cyclability and High‐Rate Capability |
title_sort |
novel bifunctional self‐stabilized strategy enabling 4.6 v licoo2 with excellent long‐term cyclability and high‐rate capability |
publisher |
Wiley |
series |
Advanced Science |
issn |
2198-3844 |
publishDate |
2019-06-01 |
description |
Abstract Although the theoretical specific capacity of LiCoO2 is as high as 274 mAh g−1, the superior electrochemical performances of LiCoO2 can be barely achieved due to the issues of severe structure destruction and LiCoO2/electrolyte interface side reactions when the upper cutoff voltage exceeds 4.5 V. Here, a bifunctional self‐stabilized strategy involving Al+Ti bulk codoping and gradient surface Mg doping is first proposed to synchronously enhance the high‐voltage (4.6 V) performances of LiCoO2. The comodified LiCoO2 (CMLCO) shows an initial discharge capacity of 224.9 mAh g−1 and 78% capacity retention after 200 cycles between 3.0 and 4.6 V. Excitingly, the CMLCO also exhibits a specific capacity of up to 142 mAh g−1 even at 10 C. Moreover, the long‐term cyclability of CMLCO/mesocarbon microbeads full cells is also enhanced significantly even at high temperature of 60 °C. The synergistic effects of this bifunctional self‐stabilized strategy on structural reversibility and interfacial stability are demonstrated by investigating the phase transitions and interface characteristics of cycled LiCoO2. This work will be a milestone breakthrough in the development of high‐voltage LiCoO2. It will also present an instructive contribution for resolving the big structural and interfacial challenges in other high‐energy‐density rechargeable batteries. |
topic |
energy storage high energy density high voltage LiCoO2 cathode structure/interface stability |
url |
https://doi.org/10.1002/advs.201900355 |
work_keys_str_mv |
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