Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-methoxy-2-oxoethylidene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enylidene]hydrazinylidene}-4-oxothiazolidin-3-yl)fumarate
The crystal structure and the conformation of the title compound, C22H27N3O7S, were determined from the synthetic pathway and by X-ray analysis. This compound is a new 4-thiazolidinone derivative prepared and isolated as pure product from thiosemicarbazone carvone. The molecule is built up from an o...
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doaj-e7d64ecc2e3c4fcdae601a49d7cd75f72020-11-25T01:17:21ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-02-0173229629910.1107/S2056989017001190xu5897Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-methoxy-2-oxoethylidene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enylidene]hydrazinylidene}-4-oxothiazolidin-3-yl)fumarateAbdellah N'ait Ousidi0My Youssef Ait Itto1Aziz Auhmani2Abdelkhalek Riahi3Abdelwahed Auhmani4Jean-Claude Daran5Laboratoire de Physico-Chimie Moléculaire et Synthèse Organique, Département de Chimie, Faculté des Sciences, Semlalia BP 2390, Marrakech 40001, MoroccoLaboratoire de Physico-Chimie Moléculaire et Synthèse Organique, Département de Chimie, Faculté des Sciences, Semlalia BP 2390, Marrakech 40001, MoroccoLaboratoire de Physico-Chimie Moléculaire et Synthèse Organique, Département de Chimie, Faculté des Sciences, Semlalia BP 2390, Marrakech 40001, MoroccoInstitut de Chimie Moléculaire de Reims, CNRS UMR 7312 Bât., Europol'Agro - Moulin de la Housse UFR Sciences BP 1039-51687 Reims Cédex 2, FranceLaboratoire de Physico-Chimie Moléculaire et Synthèse Organique, Département de Chimie, Faculté des Sciences, Semlalia BP 2390, Marrakech 40001, MoroccoLaboratoire de Chimie de Coordination, CNRS UPR8241, 205 route de Narbonne, 31077 Toulouse Cedex 04, FranceThe crystal structure and the conformation of the title compound, C22H27N3O7S, were determined from the synthetic pathway and by X-ray analysis. This compound is a new 4-thiazolidinone derivative prepared and isolated as pure product from thiosemicarbazone carvone. The molecule is built up from an oxothiazolidine ring tetrasubstituted by a methoxy–oxoethylidene, a maleate, an oxygen and a cyclohexylidene–hydrazone. The cyclohexylidene ring is statistically disordered over two positions, resulting in an inversion of configuration for the substituted carbon.http://scripts.iucr.org/cgi-bin/paper?S2056989017001190crystal structureheterocyclic compoundsthiazolidine derivativesnatural product |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Abdellah N'ait Ousidi My Youssef Ait Itto Aziz Auhmani Abdelkhalek Riahi Abdelwahed Auhmani Jean-Claude Daran |
spellingShingle |
Abdellah N'ait Ousidi My Youssef Ait Itto Aziz Auhmani Abdelkhalek Riahi Abdelwahed Auhmani Jean-Claude Daran Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-methoxy-2-oxoethylidene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enylidene]hydrazinylidene}-4-oxothiazolidin-3-yl)fumarate Acta Crystallographica Section E: Crystallographic Communications crystal structure heterocyclic compounds thiazolidine derivatives natural product |
author_facet |
Abdellah N'ait Ousidi My Youssef Ait Itto Aziz Auhmani Abdelkhalek Riahi Abdelwahed Auhmani Jean-Claude Daran |
author_sort |
Abdellah N'ait Ousidi |
title |
Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-methoxy-2-oxoethylidene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enylidene]hydrazinylidene}-4-oxothiazolidin-3-yl)fumarate |
title_short |
Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-methoxy-2-oxoethylidene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enylidene]hydrazinylidene}-4-oxothiazolidin-3-yl)fumarate |
title_full |
Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-methoxy-2-oxoethylidene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enylidene]hydrazinylidene}-4-oxothiazolidin-3-yl)fumarate |
title_fullStr |
Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-methoxy-2-oxoethylidene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enylidene]hydrazinylidene}-4-oxothiazolidin-3-yl)fumarate |
title_full_unstemmed |
Crystal structure of dimethyl 2-((2Z,5Z)-5-(2-methoxy-2-oxoethylidene)-2-{(E)-[2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enylidene]hydrazinylidene}-4-oxothiazolidin-3-yl)fumarate |
title_sort |
crystal structure of dimethyl 2-((2z,5z)-5-(2-methoxy-2-oxoethylidene)-2-{(e)-[2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enylidene]hydrazinylidene}-4-oxothiazolidin-3-yl)fumarate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2017-02-01 |
description |
The crystal structure and the conformation of the title compound, C22H27N3O7S, were determined from the synthetic pathway and by X-ray analysis. This compound is a new 4-thiazolidinone derivative prepared and isolated as pure product from thiosemicarbazone carvone. The molecule is built up from an oxothiazolidine ring tetrasubstituted by a methoxy–oxoethylidene, a maleate, an oxygen and a cyclohexylidene–hydrazone. The cyclohexylidene ring is statistically disordered over two positions, resulting in an inversion of configuration for the substituted carbon. |
topic |
crystal structure heterocyclic compounds thiazolidine derivatives natural product |
url |
http://scripts.iucr.org/cgi-bin/paper?S2056989017001190 |
work_keys_str_mv |
AT abdellahnaitousidi crystalstructureofdimethyl22z5z52methoxy2oxoethylidene2e2methyl5prop1en2ylcyclohex2enylidenehydrazinylidene4oxothiazolidin3ylfumarate AT myyoussefaititto crystalstructureofdimethyl22z5z52methoxy2oxoethylidene2e2methyl5prop1en2ylcyclohex2enylidenehydrazinylidene4oxothiazolidin3ylfumarate AT azizauhmani crystalstructureofdimethyl22z5z52methoxy2oxoethylidene2e2methyl5prop1en2ylcyclohex2enylidenehydrazinylidene4oxothiazolidin3ylfumarate AT abdelkhalekriahi crystalstructureofdimethyl22z5z52methoxy2oxoethylidene2e2methyl5prop1en2ylcyclohex2enylidenehydrazinylidene4oxothiazolidin3ylfumarate AT abdelwahedauhmani crystalstructureofdimethyl22z5z52methoxy2oxoethylidene2e2methyl5prop1en2ylcyclohex2enylidenehydrazinylidene4oxothiazolidin3ylfumarate AT jeanclaudedaran crystalstructureofdimethyl22z5z52methoxy2oxoethylidene2e2methyl5prop1en2ylcyclohex2enylidenehydrazinylidene4oxothiazolidin3ylfumarate |
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1725146369697513472 |