A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II)

A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II)

The title complex, [Co(C8H12N2O3)2(C3H4N2)2], whose structure was first determined by Wang & Craven [(1971). J. Chem. Soc. D, pp. 290–291], has been redetermined with improved precision. A crystallographic twofold rotation axis passes through the Co atom, which is tetrahedrally coordin...

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Main Authors: Wen-Dong Song, Peng-Zhi Hong, Run-Zhen Fan
Format: Article
Language:English
Published: International Union of Crystallography 2008-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807067815
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spelling doaj-e807b8b1a63a415f9f4fa812f33d11e42020-11-25T02:00:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m289m28910.1107/S1600536807067815A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II)Wen-Dong SongPeng-Zhi HongRun-Zhen FanThe title complex, [Co(C8H12N2O3)2(C3H4N2)2], whose structure was first determined by Wang & Craven [(1971). J. Chem. Soc. D, pp. 290–291], has been redetermined with improved precision. A crystallographic twofold rotation axis passes through the Co atom, which is tetrahedrally coordinated by two N atoms from two barbital ligands and two N atoms from two imidazole ligands. The molecules are self-assembled via intermolecular N—H...O hydrogen-bonding interactions into a supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536807067815
collection DOAJ
language English
format Article
sources DOAJ
author Wen-Dong Song
Peng-Zhi Hong
Run-Zhen Fan
spellingShingle Wen-Dong Song
Peng-Zhi Hong
Run-Zhen Fan
A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II)
Acta Crystallographica Section E
author_facet Wen-Dong Song
Peng-Zhi Hong
Run-Zhen Fan
author_sort Wen-Dong Song
title A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II)
title_short A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II)
title_full A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II)
title_fullStr A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II)
title_full_unstemmed A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II)
title_sort redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-02-01
description The title complex, [Co(C8H12N2O3)2(C3H4N2)2], whose structure was first determined by Wang & Craven [(1971). J. Chem. Soc. D, pp. 290–291], has been redetermined with improved precision. A crystallographic twofold rotation axis passes through the Co atom, which is tetrahedrally coordinated by two N atoms from two barbital ligands and two N atoms from two imidazole ligands. The molecules are self-assembled via intermolecular N—H...O hydrogen-bonding interactions into a supramolecular network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807067815
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AT pengzhihong redeterminationofbis558242diethylbarbituratobisimidazolecobaltii
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