Measurement and Modeling of Mean Ionic Activity Coefficient in Aqueous Solution Containing NaNO3 and Poly Ethylene Glycol

Potentiometric investigation on {H2O+NaNO3+PEG1500} mixtures were made at T=308.15K, using electrochemical cells with two ion-selective electrodes, (Na+ glass) as the cation ion-selective electrode against (NO3- solvent-polymer PVC) as the anion ion-selective electrode. The mean ionic activity coeff...

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Main Authors:	Siamak Modarresi, Mohammad Reza Dehghani, Parinaz Alimardani, Sara Kazemi Sabzvar, Farzaneh Feyzi
Format:	Article
Language:	English
Published:	Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2013-06-01
Series:	Iranian Journal of Chemistry & Chemical Engineering
Subjects:	activity coefficient polymer electrolyte solution ion-selective electrode
Online Access:	http://www.ijcce.ac.ir/article_5865_e2fbb73d0a550f376e0950dabf913a1f.pdf

id	doaj-e82ed7a04117446493cf0b7d3a952226
record_format	Article
spelling	doaj-e82ed7a04117446493cf0b7d3a9522262020-11-25T03:40:33ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering 1021-99861021-99862013-06-0132231395865Measurement and Modeling of Mean Ionic Activity Coefficient in Aqueous Solution Containing NaNO3 and Poly Ethylene GlycolSiamak Modarresi0Mohammad Reza Dehghani1Parinaz Alimardani2Sara Kazemi Sabzvar3Farzaneh Feyzi4Chemical Engineering Department, Iran University of Science and Technology, Tehran, I.R. IRANChemical Engineering Department, Iran University of Science and Technology, Tehran, I.R. IRANChemical Engineering Department, Iran University of Science and Technology, Tehran, I.R. IRANChemical Engineering Department, Iran University of Science and Technology, Tehran, I.R. IRANChemical Engineering Department, Iran University of Science and Technology, Tehran, I.R. IRANPotentiometric investigation on {H2O+NaNO3+PEG1500} mixtures were made at T=308.15K, using electrochemical cells with two ion-selective electrodes, (Na+ glass) as the cation ion-selective electrode against (NO3- solvent-polymer PVC) as the anion ion-selective electrode. The mean ionic activity coefficients of NaNO3 were measured at different concentrations of NaNO3 and PEG. Maximum concentration of electrolyte and PEG were 1 mol/kg and 0.12 mol/kg, respectively. The experimental data was modeled by utilizing the modified Pitzer equation and the activity coefficient ratio of PEG was evaluated by using Maxwell’s cross differential relation.http://www.ijcce.ac.ir/article_5865_e2fbb73d0a550f376e0950dabf913a1f.pdfactivity coefficientpolymerelectrolyte solutionion-selective electrode
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Siamak Modarresi Mohammad Reza Dehghani Parinaz Alimardani Sara Kazemi Sabzvar Farzaneh Feyzi
spellingShingle	Siamak Modarresi Mohammad Reza Dehghani Parinaz Alimardani Sara Kazemi Sabzvar Farzaneh Feyzi Measurement and Modeling of Mean Ionic Activity Coefficient in Aqueous Solution Containing NaNO3 and Poly Ethylene Glycol Iranian Journal of Chemistry & Chemical Engineering activity coefficient polymer electrolyte solution ion-selective electrode
author_facet	Siamak Modarresi Mohammad Reza Dehghani Parinaz Alimardani Sara Kazemi Sabzvar Farzaneh Feyzi
author_sort	Siamak Modarresi
title	Measurement and Modeling of Mean Ionic Activity Coefficient in Aqueous Solution Containing NaNO3 and Poly Ethylene Glycol
title_short	Measurement and Modeling of Mean Ionic Activity Coefficient in Aqueous Solution Containing NaNO3 and Poly Ethylene Glycol
title_full	Measurement and Modeling of Mean Ionic Activity Coefficient in Aqueous Solution Containing NaNO3 and Poly Ethylene Glycol
title_fullStr	Measurement and Modeling of Mean Ionic Activity Coefficient in Aqueous Solution Containing NaNO3 and Poly Ethylene Glycol
title_full_unstemmed	Measurement and Modeling of Mean Ionic Activity Coefficient in Aqueous Solution Containing NaNO3 and Poly Ethylene Glycol
title_sort	measurement and modeling of mean ionic activity coefficient in aqueous solution containing nano3 and poly ethylene glycol
publisher	Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
series	Iranian Journal of Chemistry & Chemical Engineering
issn	1021-9986 1021-9986
publishDate	2013-06-01
description	Potentiometric investigation on {H2O+NaNO3+PEG1500} mixtures were made at T=308.15K, using electrochemical cells with two ion-selective electrodes, (Na+ glass) as the cation ion-selective electrode against (NO3- solvent-polymer PVC) as the anion ion-selective electrode. The mean ionic activity coefficients of NaNO3 were measured at different concentrations of NaNO3 and PEG. Maximum concentration of electrolyte and PEG were 1 mol/kg and 0.12 mol/kg, respectively. The experimental data was modeled by utilizing the modified Pitzer equation and the activity coefficient ratio of PEG was evaluated by using Maxwell’s cross differential relation.
topic	activity coefficient polymer electrolyte solution ion-selective electrode
url	http://www.ijcce.ac.ir/article_5865_e2fbb73d0a550f376e0950dabf913a1f.pdf
work_keys_str_mv	AT siamakmodarresi measurementandmodelingofmeanionicactivitycoefficientinaqueoussolutioncontainingnano3andpolyethyleneglycol AT mohammadrezadehghani measurementandmodelingofmeanionicactivitycoefficientinaqueoussolutioncontainingnano3andpolyethyleneglycol AT parinazalimardani measurementandmodelingofmeanionicactivitycoefficientinaqueoussolutioncontainingnano3andpolyethyleneglycol AT sarakazemisabzvar measurementandmodelingofmeanionicactivitycoefficientinaqueoussolutioncontainingnano3andpolyethyleneglycol AT farzanehfeyzi measurementandmodelingofmeanionicactivitycoefficientinaqueoussolutioncontainingnano3andpolyethyleneglycol
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Measurement and Modeling of Mean Ionic Activity Coefficient in Aqueous Solution Containing NaNO3 and Poly Ethylene Glycol

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