[N,N-Bis(2-pyridylmethyl)glycinato-κ4N,N′,N′′,O]dichloridoiron(III)–[N,N-bis(2-pyridylmethyl)glycine-κ4N,N′,N′′,O]dichloridozinc(II) (1/1)

[N,N-Bis(2-pyridylmethyl)glycinato-κ4N,N′,N′′,O]dichloridoiron(III)–[N,N-bis(2-pyridylmethyl)glycine-κ4N,N′,N′′,O]dichloridozinc(II) (1/1)

The title compound, [Fe(C14H14N3O2)Cl2]·[ZnCl2(C14H15N3O2)], is formulated as [FeIII(bpg)Cl2][ZnIICl2(bpgH)], where bpg is the tetradentate ligand N,N-bis(2-pyridylmethyl)glycine. The structure contains one crystallographically distinct complex with FeIII and ZnII atoms present in a 50:...

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Main Authors: Andrew D. Bond, Christine J. McKenzie, Anne Nielsen
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809051022
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spelling doaj-e836e5548843480faf19435beeecefa32020-11-25T02:19:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1706m170610.1107/S1600536809051022[N,N-Bis(2-pyridylmethyl)glycinato-κ4N,N′,N′′,O]dichloridoiron(III)–[N,N-bis(2-pyridylmethyl)glycine-κ4N,N′,N′′,O]dichloridozinc(II) (1/1)Andrew D. BondChristine J. McKenzieAnne NielsenThe title compound, [Fe(C14H14N3O2)Cl2]·[ZnCl2(C14H15N3O2)], is formulated as [FeIII(bpg)Cl2][ZnIICl2(bpgH)], where bpg is the tetradentate ligand N,N-bis(2-pyridylmethyl)glycine. The structure contains one crystallographically distinct complex with FeIII and ZnII atoms present in a 50:50 ratio in a single-atom site. The non-coordinated O atoms of the carboxyl groups of bpg meet across crystallographic inversion centres, forming O—H...O hydrogen bonds that include only one H atom per two complexes, consistent with the 1:1 disorder of FeIII and ZnII. http://scripts.iucr.org/cgi-bin/paper?S1600536809051022
collection DOAJ
language English
format Article
sources DOAJ
author Andrew D. Bond
Christine J. McKenzie
Anne Nielsen
spellingShingle Andrew D. Bond
Christine J. McKenzie
Anne Nielsen
[N,N-Bis(2-pyridylmethyl)glycinato-κ4N,N′,N′′,O]dichloridoiron(III)–[N,N-bis(2-pyridylmethyl)glycine-κ4N,N′,N′′,O]dichloridozinc(II) (1/1)
Acta Crystallographica Section E
author_facet Andrew D. Bond
Christine J. McKenzie
Anne Nielsen
author_sort Andrew D. Bond
title [N,N-Bis(2-pyridylmethyl)glycinato-κ4N,N′,N′′,O]dichloridoiron(III)–[N,N-bis(2-pyridylmethyl)glycine-κ4N,N′,N′′,O]dichloridozinc(II) (1/1)
title_short [N,N-Bis(2-pyridylmethyl)glycinato-κ4N,N′,N′′,O]dichloridoiron(III)–[N,N-bis(2-pyridylmethyl)glycine-κ4N,N′,N′′,O]dichloridozinc(II) (1/1)
title_full [N,N-Bis(2-pyridylmethyl)glycinato-κ4N,N′,N′′,O]dichloridoiron(III)–[N,N-bis(2-pyridylmethyl)glycine-κ4N,N′,N′′,O]dichloridozinc(II) (1/1)
title_fullStr [N,N-Bis(2-pyridylmethyl)glycinato-κ4N,N′,N′′,O]dichloridoiron(III)–[N,N-bis(2-pyridylmethyl)glycine-κ4N,N′,N′′,O]dichloridozinc(II) (1/1)
title_full_unstemmed [N,N-Bis(2-pyridylmethyl)glycinato-κ4N,N′,N′′,O]dichloridoiron(III)–[N,N-bis(2-pyridylmethyl)glycine-κ4N,N′,N′′,O]dichloridozinc(II) (1/1)
title_sort [n,n-bis(2-pyridylmethyl)glycinato-κ4n,n′,n′′,o]dichloridoiron(iii)–[n,n-bis(2-pyridylmethyl)glycine-κ4n,n′,n′′,o]dichloridozinc(ii) (1/1)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description The title compound, [Fe(C14H14N3O2)Cl2]·[ZnCl2(C14H15N3O2)], is formulated as [FeIII(bpg)Cl2][ZnIICl2(bpgH)], where bpg is the tetradentate ligand N,N-bis(2-pyridylmethyl)glycine. The structure contains one crystallographically distinct complex with FeIII and ZnII atoms present in a 50:50 ratio in a single-atom site. The non-coordinated O atoms of the carboxyl groups of bpg meet across crystallographic inversion centres, forming O—H...O hydrogen bonds that include only one H atom per two complexes, consistent with the 1:1 disorder of FeIII and ZnII.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809051022
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AT christinejmckenzie nnbis2pyridylmethylglycinatoamp9544nnamp8242namp8242amp8242odichloridoironiiiamp8211nnbis2pyridylmethylglycineamp9544nnamp8242namp8242amp8242odichloridozincii11
AT annenielsen nnbis2pyridylmethylglycinatoamp9544nnamp8242namp8242amp8242odichloridoironiiiamp8211nnbis2pyridylmethylglycineamp9544nnamp8242namp8242amp8242odichloridozincii11
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