Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)]
In the title centrosymmetric dinuclear EuIII complex, [Eu2(CH3COO)6(C12H8N2)2], each EuIII cation is coordinated by seven O atoms from five acetate anions and two N atoms from one phenanthroline ligand in a distorted tricapped trigonal-prismatic geometry. Four acetate anions bridge two EuIII cations...
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International Union of Crystallography
2010-06-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810015680 |
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doaj-e8520de908db4b5bae4f2ddd867abc2d2020-11-25T02:07:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m606m60610.1107/S1600536810015680Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)]Wen-Jing LiuZhao-Yang LiZhi-Qiang WeiShan-Tang YueIn the title centrosymmetric dinuclear EuIII complex, [Eu2(CH3COO)6(C12H8N2)2], each EuIII cation is coordinated by seven O atoms from five acetate anions and two N atoms from one phenanthroline ligand in a distorted tricapped trigonal-prismatic geometry. Four acetate anions bridge two EuIII cations to form the dinuclear complex, with an Eu...Eu distance of 3.9409 (8) Å. Weak intermolecular C—H...O hydrogen bonding is present in the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536810015680 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Wen-Jing Liu Zhao-Yang Li Zhi-Qiang Wei Shan-Tang Yue |
spellingShingle |
Wen-Jing Liu Zhao-Yang Li Zhi-Qiang Wei Shan-Tang Yue Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)] Acta Crystallographica Section E |
author_facet |
Wen-Jing Liu Zhao-Yang Li Zhi-Qiang Wei Shan-Tang Yue |
author_sort |
Wen-Jing Liu |
title |
Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)] |
title_short |
Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)] |
title_full |
Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)] |
title_fullStr |
Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)] |
title_full_unstemmed |
Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)] |
title_sort |
tetra-μ-acetato-κ4o:o′;κ3o,o′:o′;κ3o:o,o′-bis[(acetato-κ2o,o′)(1,10-phenanthroline-κ2n,n′)europium(iii)] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2010-06-01 |
description |
In the title centrosymmetric dinuclear EuIII complex, [Eu2(CH3COO)6(C12H8N2)2], each EuIII cation is coordinated by seven O atoms from five acetate anions and two N atoms from one phenanthroline ligand in a distorted tricapped trigonal-prismatic geometry. Four acetate anions bridge two EuIII cations to form the dinuclear complex, with an Eu...Eu distance of 3.9409 (8) Å. Weak intermolecular C—H...O hydrogen bonding is present in the crystal structure. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810015680 |
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