Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)]

Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)]

In the title centrosymmetric dinuclear EuIII complex, [Eu2(CH3COO)6(C12H8N2)2], each EuIII cation is coordinated by seven O atoms from five acetate anions and two N atoms from one phenanthroline ligand in a distorted tricapped trigonal-prismatic geometry. Four acetate anions bridge two EuIII cations...

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Main Authors: Wen-Jing Liu, Zhao-Yang Li, Zhi-Qiang Wei, Shan-Tang Yue
Format: Article
Language:English
Published: International Union of Crystallography 2010-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810015680
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spelling doaj-e8520de908db4b5bae4f2ddd867abc2d2020-11-25T02:07:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m606m60610.1107/S1600536810015680Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)]Wen-Jing LiuZhao-Yang LiZhi-Qiang WeiShan-Tang YueIn the title centrosymmetric dinuclear EuIII complex, [Eu2(CH3COO)6(C12H8N2)2], each EuIII cation is coordinated by seven O atoms from five acetate anions and two N atoms from one phenanthroline ligand in a distorted tricapped trigonal-prismatic geometry. Four acetate anions bridge two EuIII cations to form the dinuclear complex, with an Eu...Eu distance of 3.9409 (8) Å. Weak intermolecular C—H...O hydrogen bonding is present in the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536810015680
collection DOAJ
language English
format Article
sources DOAJ
author Wen-Jing Liu
Zhao-Yang Li
Zhi-Qiang Wei
Shan-Tang Yue
spellingShingle Wen-Jing Liu
Zhao-Yang Li
Zhi-Qiang Wei
Shan-Tang Yue
Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)]
Acta Crystallographica Section E
author_facet Wen-Jing Liu
Zhao-Yang Li
Zhi-Qiang Wei
Shan-Tang Yue
author_sort Wen-Jing Liu
title Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)]
title_short Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)]
title_full Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)]
title_fullStr Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)]
title_full_unstemmed Tetra-μ-acetato-κ4O:O′;κ3O,O′:O′;κ3O:O,O′-bis[(acetato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)europium(III)]
title_sort tetra-μ-acetato-κ4o:o′;κ3o,o′:o′;κ3o:o,o′-bis[(acetato-κ2o,o′)(1,10-phenanthroline-κ2n,n′)europium(iii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-06-01
description In the title centrosymmetric dinuclear EuIII complex, [Eu2(CH3COO)6(C12H8N2)2], each EuIII cation is coordinated by seven O atoms from five acetate anions and two N atoms from one phenanthroline ligand in a distorted tricapped trigonal-prismatic geometry. Four acetate anions bridge two EuIII cations to form the dinuclear complex, with an Eu...Eu distance of 3.9409 (8) Å. Weak intermolecular C—H...O hydrogen bonding is present in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810015680
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