Electrospun poly(ethylene oxide) nanofibrous composites with enhanced ionic conductivity as flexible solid polymer electrolytes

• Main Authors: Jun-Wei Zha, Na Huang, Kang-Qiang He, Zhi-Min Dang, Chang-Yong Shi, Robert KwokYiu Li
• Format: Article
• Language: English
• Published: Wiley 2016-11-01
• Series: High Voltage
• Subjects: nanofibres; nanocomposites; ionic conductivity; polymer electrolytes; lithium compounds; secondary cells; electrospinning; nanoparticles; electrospun poly(ethylene oxide) nanofibrous composite; enhanced ionic conductivity; flexible solid polymer electrolyte; SPE; lithium battery; Li-ion battery; liquid electrolyte; high-energy battery; poly(ethylene oxide)-lithium perchlorate; PEO–LiClO(4); mechanical property; modified TiO(2) nanofibre; TNF; TiO(2) nanoparticle; TNP; crystalline phase concentration; tensile strength; electrospinning method; temperature 20 degC; pressure 13.8 MPa
• Online Access: https://digital-library.theiet.org/content/journals/10.1049/hve.2016.0069

Solid polymer electrolytes (SPEs) have great potential to address the safety issues of lithium (Li)-ion batteries when compared with conventional liquid electrolytes, which makes them a promising alternative for next-generation high-energy batteries. In this work, poly(ethylene oxide)-lithium perchlorate (PEO–LiClO(4)) polymer electrolytes for Li-ion batteries were prepared using electrospinning. The crystallinity, ionic conductivity as well as mechanical properties were investigated. Ionic conductivities and mechanical properties of PEO–LiClO(4) based SPE have been obviously increased by incorporating modified TiO(2) nanofibres (TNFs) than TiO(2) nanoparticles (TNPs), due to that both TNFs and TNPs can decrease the crystalline phase concentration of PEO and increase segmental flexibility of PEO. The SPE with 3 wt% TNFs exhibits the highest conductivity of 5.308 × 10^−5 S cm^−1 at 20°C and higher tensile strength of 13.8 MPa. These results highlight the potential of utilising the electrospinning method to improve the ionic conductivity of SPEs.