Di-μ-methanolato-κ4O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN2)(nitrato-κO)copper(II)]

Di-μ-methanolato-κ4O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN2)(nitrato-κO)copper(II)]

Copper nitrate in methanol solution cleaves the N—Cmethanol bond when reacted with 3-methyl-5-phenylpyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu2(CH3O)2(NO3)2(C10H10N2)4], in which the CuII atom is linked to a nitrate ion, two methanolate ions and two...

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Main Authors: Xu-Guang Li, Meng-Meng Gao, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681201241X
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spelling doaj-e94b4212f3c442c1b5aa54828d1ce5e52020-11-25T00:14:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m503m50310.1107/S160053681201241XDi-μ-methanolato-κ4O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN2)(nitrato-κO)copper(II)]Xu-Guang LiMeng-Meng GaoSeik Weng NgCopper nitrate in methanol solution cleaves the N—Cmethanol bond when reacted with 3-methyl-5-phenylpyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu2(CH3O)2(NO3)2(C10H10N2)4], in which the CuII atom is linked to a nitrate ion, two methanolate ions and two pyrazole ligands in a distorted square-pyramidal environment. The O atom of the nitrate anion occupies the apical site. The crystal structure features intramolecular N—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S160053681201241X
collection DOAJ
language English
format Article
sources DOAJ
author Xu-Guang Li
Meng-Meng Gao
Seik Weng Ng
spellingShingle Xu-Guang Li
Meng-Meng Gao
Seik Weng Ng
Di-μ-methanolato-κ4O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN2)(nitrato-κO)copper(II)]
Acta Crystallographica Section E
author_facet Xu-Guang Li
Meng-Meng Gao
Seik Weng Ng
author_sort Xu-Guang Li
title Di-μ-methanolato-κ4O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN2)(nitrato-κO)copper(II)]
title_short Di-μ-methanolato-κ4O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN2)(nitrato-κO)copper(II)]
title_full Di-μ-methanolato-κ4O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN2)(nitrato-κO)copper(II)]
title_fullStr Di-μ-methanolato-κ4O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN2)(nitrato-κO)copper(II)]
title_full_unstemmed Di-μ-methanolato-κ4O:O-bis[bis(3-methyl-5-phenyl-1H-pyrazole-κN2)(nitrato-κO)copper(II)]
title_sort di-μ-methanolato-κ4o:o-bis[bis(3-methyl-5-phenyl-1h-pyrazole-κn2)(nitrato-κo)copper(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-04-01
description Copper nitrate in methanol solution cleaves the N—Cmethanol bond when reacted with 3-methyl-5-phenylpyrazole-1-methanol to yield the centrosymmetric dinuclear title compound, [Cu2(CH3O)2(NO3)2(C10H10N2)4], in which the CuII atom is linked to a nitrate ion, two methanolate ions and two pyrazole ligands in a distorted square-pyramidal environment. The O atom of the nitrate anion occupies the apical site. The crystal structure features intramolecular N—H...O hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S160053681201241X
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AT mengmenggao diamp956methanolatoamp9544oobisbis3methyl5phenyl1hpyrazoleamp954n2nitratoamp954ocopperii
AT seikwengng diamp956methanolatoamp9544oobisbis3methyl5phenyl1hpyrazoleamp954n2nitratoamp954ocopperii
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