Spectral characterization and crystal structure of 2-amino-N′-[(1Z)-1-(4-chlorophenyl)ethylidene]-benzohydrazide

Spectral characterization and crystal structure of 2-amino-N′-[(1Z)-1-(4-chlorophenyl)ethylidene]-benzohydrazide

The crystal structure of 2-amino-N′-[(1Z)-1-(4-chlorophenyl)ethylidene]benzohydrazide (I) is determined by X-ray diffraction at room temperature. The structure of I also was characterized by elemental analysis, mass, FT-IR and NMR spectroscopic techniques. The compound crystallizes in triclinic syst...

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Main Authors: Mohammad Arfan, Rasool Khan, Aydin Tavman, Sumbal Saba
Format: Article
Language:English
Published: Elsevier 2016-01-01
Series:Journal of Saudi Chemical Society
Subjects:
Crystal structure
Spectroscopy
Chlorophenyl-ethylidene
Benzohydrazide
Online Access:http://www.sciencedirect.com/science/article/pii/S1319610312001330
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spelling doaj-e952fbea642b419c9f1b7df1eb36b92a2020-11-25T00:45:28ZengElsevierJournal of Saudi Chemical Society1319-61032016-01-01201404410.1016/j.jscs.2012.08.006Spectral characterization and crystal structure of 2-amino-N′-[(1Z)-1-(4-chlorophenyl)ethylidene]-benzohydrazideMohammad Arfan0Rasool Khan1Aydin Tavman2Sumbal Saba3Institute of Chemical Sciences, University of Peshawar, Peshawar 25120, PakistanInstitute of Chemical Sciences, University of Peshawar, Peshawar 25120, PakistanIstanbul University, Faculty of Engineering, Chemistry Department, Avcilar 34320, Istanbul, TurkeyInstitute of Chemical Sciences, University of Peshawar, Peshawar 25120, PakistanThe crystal structure of 2-amino-N′-[(1Z)-1-(4-chlorophenyl)ethylidene]benzohydrazide (I) is determined by X-ray diffraction at room temperature. The structure of I also was characterized by elemental analysis, mass, FT-IR and NMR spectroscopic techniques. The compound crystallizes in triclinic system, and space group is P1¯. Unit-cell dimensions are the following: a = 7.05380(10) Å, b = 7.65490(10) Å, c = 13.7094(4) Å, V = 694.01(2) Å3, Z = 2. The title compound is nearly planar and has intermolecular N–H⋯O hydrogen bonding. According to the spectral data, I exhibits an amide-iminol tautomerism.http://www.sciencedirect.com/science/article/pii/S1319610312001330Crystal structureSpectroscopyChlorophenyl-ethylideneBenzohydrazide
collection DOAJ
language English
format Article
sources DOAJ
author Mohammad Arfan
Rasool Khan
Aydin Tavman
Sumbal Saba
spellingShingle Mohammad Arfan
Rasool Khan
Aydin Tavman
Sumbal Saba
Spectral characterization and crystal structure of 2-amino-N′-[(1Z)-1-(4-chlorophenyl)ethylidene]-benzohydrazide
Journal of Saudi Chemical Society
Crystal structure
Spectroscopy
Chlorophenyl-ethylidene
Benzohydrazide
author_facet Mohammad Arfan
Rasool Khan
Aydin Tavman
Sumbal Saba
author_sort Mohammad Arfan
title Spectral characterization and crystal structure of 2-amino-N′-[(1Z)-1-(4-chlorophenyl)ethylidene]-benzohydrazide
title_short Spectral characterization and crystal structure of 2-amino-N′-[(1Z)-1-(4-chlorophenyl)ethylidene]-benzohydrazide
title_full Spectral characterization and crystal structure of 2-amino-N′-[(1Z)-1-(4-chlorophenyl)ethylidene]-benzohydrazide
title_fullStr Spectral characterization and crystal structure of 2-amino-N′-[(1Z)-1-(4-chlorophenyl)ethylidene]-benzohydrazide
title_full_unstemmed Spectral characterization and crystal structure of 2-amino-N′-[(1Z)-1-(4-chlorophenyl)ethylidene]-benzohydrazide
title_sort spectral characterization and crystal structure of 2-amino-n′-[(1z)-1-(4-chlorophenyl)ethylidene]-benzohydrazide
publisher Elsevier
series Journal of Saudi Chemical Society
issn 1319-6103
publishDate 2016-01-01
description The crystal structure of 2-amino-N′-[(1Z)-1-(4-chlorophenyl)ethylidene]benzohydrazide (I) is determined by X-ray diffraction at room temperature. The structure of I also was characterized by elemental analysis, mass, FT-IR and NMR spectroscopic techniques. The compound crystallizes in triclinic system, and space group is P1¯. Unit-cell dimensions are the following: a = 7.05380(10) Å, b = 7.65490(10) Å, c = 13.7094(4) Å, V = 694.01(2) Å3, Z = 2. The title compound is nearly planar and has intermolecular N–H⋯O hydrogen bonding. According to the spectral data, I exhibits an amide-iminol tautomerism.
topic Crystal structure
Spectroscopy
Chlorophenyl-ethylidene
Benzohydrazide
url http://www.sciencedirect.com/science/article/pii/S1319610312001330
work_keys_str_mv AT mohammadarfan spectralcharacterizationandcrystalstructureof2aminon1z14chlorophenylethylidenebenzohydrazide
AT rasoolkhan spectralcharacterizationandcrystalstructureof2aminon1z14chlorophenylethylidenebenzohydrazide
AT aydintavman spectralcharacterizationandcrystalstructureof2aminon1z14chlorophenylethylidenebenzohydrazide
AT sumbalsaba spectralcharacterizationandcrystalstructureof2aminon1z14chlorophenylethylidenebenzohydrazide
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