Bis(2,S-dimethyldithiocarbazate-κ2N3,S)(nitrato-κO)copper(II) nitrate

Bis(2,S-dimethyldithiocarbazate-κ2N3,S)(nitrato-κO)copper(II) nitrate

The title complex, [Cu(NO3)(C3H8N2S2)2]NO3, represents a low-symmetry polymorph (P-1, Z = 4) of a previously reported form [P-1, Z = 2; Ali et al. (2011). Polyhedron, 30, 542–548]. The CuII atom in each independent cation is found within a distorted square-pyramidal N2S2O coordination...

Full description

Bibliographic Details
Main Authors: Saroj K. S. Hazari, B. K. Dey, B. Ganguly, Seik Weng Ng, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812021423
id doaj-e984842966cc442b89b89bf70f4bfc12
record_format Article
spelling doaj-e984842966cc442b89b89bf70f4bfc122020-11-25T02:00:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m779m78010.1107/S1600536812021423Bis(2,S-dimethyldithiocarbazate-κ2N3,S)(nitrato-κO)copper(II) nitrateSaroj K. S. HazariB. K. DeyB. GangulySeik Weng NgEdward R. T. TiekinkThe title complex, [Cu(NO3)(C3H8N2S2)2]NO3, represents a low-symmetry polymorph (P-1, Z = 4) of a previously reported form [P-1, Z = 2; Ali et al. (2011). Polyhedron, 30, 542–548]. The CuII atom in each independent cation is found within a distorted square-pyramidal N2S2O coordination geometry defined by two N,S-bidentate ligands and an O atom derived from a monodentate nitrate. The primary difference between the cations is found in the relative orientations of the coordinated nitrate groups, which are directed to opposite sides of the molecule. Supramolecular layers along [110] and sustained by N—H...O interactions feature in the crystal packing. These are connected along the c axis by C—H...O interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536812021423
collection DOAJ
language English
format Article
sources DOAJ
author Saroj K. S. Hazari
B. K. Dey
B. Ganguly
Seik Weng Ng
Edward R. T. Tiekink
spellingShingle Saroj K. S. Hazari
B. K. Dey
B. Ganguly
Seik Weng Ng
Edward R. T. Tiekink
Bis(2,S-dimethyldithiocarbazate-κ2N3,S)(nitrato-κO)copper(II) nitrate
Acta Crystallographica Section E
author_facet Saroj K. S. Hazari
B. K. Dey
B. Ganguly
Seik Weng Ng
Edward R. T. Tiekink
author_sort Saroj K. S. Hazari
title Bis(2,S-dimethyldithiocarbazate-κ2N3,S)(nitrato-κO)copper(II) nitrate
title_short Bis(2,S-dimethyldithiocarbazate-κ2N3,S)(nitrato-κO)copper(II) nitrate
title_full Bis(2,S-dimethyldithiocarbazate-κ2N3,S)(nitrato-κO)copper(II) nitrate
title_fullStr Bis(2,S-dimethyldithiocarbazate-κ2N3,S)(nitrato-κO)copper(II) nitrate
title_full_unstemmed Bis(2,S-dimethyldithiocarbazate-κ2N3,S)(nitrato-κO)copper(II) nitrate
title_sort bis(2,s-dimethyldithiocarbazate-κ2n3,s)(nitrato-κo)copper(ii) nitrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description The title complex, [Cu(NO3)(C3H8N2S2)2]NO3, represents a low-symmetry polymorph (P-1, Z = 4) of a previously reported form [P-1, Z = 2; Ali et al. (2011). Polyhedron, 30, 542–548]. The CuII atom in each independent cation is found within a distorted square-pyramidal N2S2O coordination geometry defined by two N,S-bidentate ligands and an O atom derived from a monodentate nitrate. The primary difference between the cations is found in the relative orientations of the coordinated nitrate groups, which are directed to opposite sides of the molecule. Supramolecular layers along [110] and sustained by N—H...O interactions feature in the crystal packing. These are connected along the c axis by C—H...O interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812021423
work_keys_str_mv AT sarojkshazari bis2sdimethyldithiocarbazateamp9542n3snitratoamp954ocopperiinitrate
AT bkdey bis2sdimethyldithiocarbazateamp9542n3snitratoamp954ocopperiinitrate
AT bganguly bis2sdimethyldithiocarbazateamp9542n3snitratoamp954ocopperiinitrate
AT seikwengng bis2sdimethyldithiocarbazateamp9542n3snitratoamp954ocopperiinitrate
AT edwardrttiekink bis2sdimethyldithiocarbazateamp9542n3snitratoamp954ocopperiinitrate
_version_ 1724962033534763008

Similar Items