Catalytic Enantioselective Reactions with (Benzo)Pyrylium Salts

Catalytic Enantioselective Reactions with (Benzo)Pyrylium Salts

The use of (benzo)pyrylium salts as versatile synthetic building blocks has become an attractive platform for the preparation of valuable heterocyclic compounds. Besides other numerous direct applications of (benzo)pyryliums, the intrinsic electrophilic nature of these species or the dipole characte...

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Main Authors: Sumi Joseph, Gaukhar Khassenova, Olga Garcia Mancheno
Format: Article
Language:deu
Published: Swiss Chemical Society 2020-11-01
Series:CHIMIA
Subjects:
enantioselective catalysis
metal catalysis
o-heterocycles
organocatalysis
pyrylium salts
Online Access:https://www.ingentaconnect.com/content/scs/chimia/2020/00000074/00000011/art00003
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spelling doaj-e98e8197a5b441818da71c53ba90a1632020-11-27T12:14:51ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24242020-11-01741185786510.2533/chimia.2020.857Catalytic Enantioselective Reactions with (Benzo)Pyrylium SaltsSumi Joseph0Gaukhar Khassenova1Olga Garcia Mancheno2Organic Chemistry Institute, Münster University, Corrensstrasse 36, D-48149 Münster, Germany 2: Organic Chemistry Institute, Münster University, Corrensstrasse 36, D-48149 Münster, GermanyOrganic Chemistry Institute, Münster University, Corrensstrasse 36, D-48149 Münster, Germany 2: Organic Chemistry Institute, Münster University, Corrensstrasse 36, D-48149 Münster, GermanyOrganic Chemistry Institute, Münster University, Corrensstrasse 36, D-48149 Münster, Germany 2: Organic Chemistry Institute, Münster University, Corrensstrasse 36, D-48149 Münster, GermanyThe use of (benzo)pyrylium salts as versatile synthetic building blocks has become an attractive platform for the preparation of valuable heterocyclic compounds. Besides other numerous direct applications of (benzo)pyryliums, the intrinsic electrophilic nature of these species or the dipole character of the related oxidopyrylium derivatives have been exploited towards the development of enantioselective transformations such as nucleophilic dearomatization and cycloaddition reactions. This review aims at providing an overview on the relevant catalytic enantioselective methodologies developed in the past years, which are presented considering the involved metal- and/or organic catalytic system, as well as the type of reaction.https://www.ingentaconnect.com/content/scs/chimia/2020/00000074/00000011/art00003enantioselective catalysismetal catalysiso-heterocyclesorganocatalysispyrylium salts
collection DOAJ
language deu
format Article
sources DOAJ
author Sumi Joseph
Gaukhar Khassenova
Olga Garcia Mancheno
spellingShingle Sumi Joseph
Gaukhar Khassenova
Olga Garcia Mancheno
Catalytic Enantioselective Reactions with (Benzo)Pyrylium Salts
CHIMIA
enantioselective catalysis
metal catalysis
o-heterocycles
organocatalysis
pyrylium salts
author_facet Sumi Joseph
Gaukhar Khassenova
Olga Garcia Mancheno
author_sort Sumi Joseph
title Catalytic Enantioselective Reactions with (Benzo)Pyrylium Salts
title_short Catalytic Enantioselective Reactions with (Benzo)Pyrylium Salts
title_full Catalytic Enantioselective Reactions with (Benzo)Pyrylium Salts
title_fullStr Catalytic Enantioselective Reactions with (Benzo)Pyrylium Salts
title_full_unstemmed Catalytic Enantioselective Reactions with (Benzo)Pyrylium Salts
title_sort catalytic enantioselective reactions with (benzo)pyrylium salts
publisher Swiss Chemical Society
series CHIMIA
issn 0009-4293
2673-2424
publishDate 2020-11-01
description The use of (benzo)pyrylium salts as versatile synthetic building blocks has become an attractive platform for the preparation of valuable heterocyclic compounds. Besides other numerous direct applications of (benzo)pyryliums, the intrinsic electrophilic nature of these species or the dipole character of the related oxidopyrylium derivatives have been exploited towards the development of enantioselective transformations such as nucleophilic dearomatization and cycloaddition reactions. This review aims at providing an overview on the relevant catalytic enantioselective methodologies developed in the past years, which are presented considering the involved metal- and/or organic catalytic system, as well as the type of reaction.
topic enantioselective catalysis
metal catalysis
o-heterocycles
organocatalysis
pyrylium salts
url https://www.ingentaconnect.com/content/scs/chimia/2020/00000074/00000011/art00003
work_keys_str_mv AT sumijoseph catalyticenantioselectivereactionswithbenzopyryliumsalts
AT gaukharkhassenova catalyticenantioselectivereactionswithbenzopyryliumsalts
AT olgagarciamancheno catalyticenantioselectivereactionswithbenzopyryliumsalts
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