A simple empirical model estimating atmospheric CO₂ background concentrations

• Main Authors: H. Bovensmann, A. J. Cogan, S. Guerlet, J. Heymann, F. Hase, O. Schneising, M. Buchwitz, M. Reuter, J. P. Burrows
• Format: Article
• Language: English
• Published: Copernicus Publications 2012-06-01
• Series: Atmospheric Measurement Techniques
• Online Access: http://www.atmos-meas-tech.net/5/1349/2012/amt-5-1349-2012.pdf

A simple empirical CO₂ model (SECM) is presented to estimate column-average dry-air mole fractions of atmospheric CO₂ (XCO₂) as well as mixing ratio profiles. SECM is based on a simple equation depending on 17 empirical parameters, latitude, and date. The empirical parameters have been determined by least squares fitting to NOAA's (National Oceanic and Atmospheric Administration) assimilation system CarbonTracker version 2010 (CT2010). Comparisons with TCCON (total carbon column observing network) FTS (Fourier transform spectrometer) measurements show that SECM XCO₂ agrees quite well with reality. The synthetic XCO₂ values have a standard error of 1.39 ppm and systematic station-to-station biases of 0.46 ppm. Typical column averaging kernels of the TCCON FTS, a SCIAMACHY (Scanning Imaging Absorption Spectrometer for Atmospheric CHartographY), and two GOSAT (Greenhouse gases Observing SATellite) XCO₂ retrieval algorithms have been used to assess the smoothing error introduced by using SECM profiles instead of CT2010 profiles as a priori. The additional smoothing error amounts to 0.17 ppm for a typical SCIAMACHY averaging kernel and is most times much smaller for the other instruments (e.g. 0.05 ppm for a typical TCCON FTS averaging kernel). Therefore, SECM is well suited to provide a priori information for state-of-the-art ground-based (FTS) and satellite-based (GOSAT, SCIAMACHY) XCO₂ retrievals. Other potential applications are: (i) near real-time processing systems (that cannot make use of models like CT2010 operated in delayed mode), (ii) "CO₂ proxy" methods for XCH₄ retrievals (as correction for the XCO₂ background), and (iii) observing system simulation experiments especially for future satellite missions.