Dichloridobis(isoquinoline-κN)zinc(II)

In the title compound, [ZnCl2(C9H7N)2], the ZnII cation is coordinated by two Cl− anions and two isoquinoline ligands in a distorted ZnCl2N2 tetrahedral geometry; the two isoquinoline ring systems are twisted with respect to each other at a dihedral angle of 45.72 (8)&...

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Main Authors: Meng-Jiao Li, Jing-Jing Nie, Duan-Jun Xu
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810024803
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spelling doaj-eaccc3449f864c5bae50c8b123d0e41b2020-11-24T21:56:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m876m87610.1107/S1600536810024803Dichloridobis(isoquinoline-κN)zinc(II)Meng-Jiao LiJing-Jing NieDuan-Jun XuIn the title compound, [ZnCl2(C9H7N)2], the ZnII cation is coordinated by two Cl− anions and two isoquinoline ligands in a distorted ZnCl2N2 tetrahedral geometry; the two isoquinoline ring systems are twisted with respect to each other at a dihedral angle of 45.72 (8)°. The parallel isoqiunoline ring systems of adjacent molecules are partially overlapped, with the shorter face-to-face distance of 3.438 (19) Å indicating the existence of weak π–π stacking in the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536810024803
collection DOAJ
language English
format Article
sources DOAJ
author Meng-Jiao Li
Jing-Jing Nie
Duan-Jun Xu
spellingShingle Meng-Jiao Li
Jing-Jing Nie
Duan-Jun Xu
Dichloridobis(isoquinoline-κN)zinc(II)
Acta Crystallographica Section E
author_facet Meng-Jiao Li
Jing-Jing Nie
Duan-Jun Xu
author_sort Meng-Jiao Li
title Dichloridobis(isoquinoline-κN)zinc(II)
title_short Dichloridobis(isoquinoline-κN)zinc(II)
title_full Dichloridobis(isoquinoline-κN)zinc(II)
title_fullStr Dichloridobis(isoquinoline-κN)zinc(II)
title_full_unstemmed Dichloridobis(isoquinoline-κN)zinc(II)
title_sort dichloridobis(isoquinoline-κn)zinc(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-08-01
description In the title compound, [ZnCl2(C9H7N)2], the ZnII cation is coordinated by two Cl− anions and two isoquinoline ligands in a distorted ZnCl2N2 tetrahedral geometry; the two isoquinoline ring systems are twisted with respect to each other at a dihedral angle of 45.72 (8)°. The parallel isoqiunoline ring systems of adjacent molecules are partially overlapped, with the shorter face-to-face distance of 3.438 (19) Å indicating the existence of weak π–π stacking in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810024803
work_keys_str_mv AT mengjiaoli dichloridobisisoquinolineamp954nzincii
AT jingjingnie dichloridobisisoquinolineamp954nzincii
AT duanjunxu dichloridobisisoquinolineamp954nzincii
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