The Early History of Polyaniline: Discovery and Origins

Prior to the discovery of its conductive properties in the 1960s, polyaniline was studied and applied as a variety of colored materials and dyes. The history of the discovery and origins of polyaniline are presented beginning with the initial oxidation of aniline by F. Ferdinand Runge in 1834 and c...

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Main Author: Seth C. Rasmussen
Format: Article
Language:English
Published: Firenze University Press 2017-10-01
Series:Substantia
Subjects:
Online Access:https://riviste.fupress.net/index.php/subs/article/view/30
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spelling doaj-ec51f65b1043464d9917d36bfd2a5f112020-11-24T21:13:40ZengFirenze University PressSubstantia2532-39972017-10-011210.13128/Substantia-3030The Early History of Polyaniline: Discovery and OriginsSeth C. Rasmussen0Department of Chemistry and Biochemistry, North Dakota State University, NDSU Dept. 2735, P.O. Box 6050, Fargo, ND 58108-6050, USA Prior to the discovery of its conductive properties in the 1960s, polyaniline was studied and applied as a variety of colored materials and dyes. The history of the discovery and origins of polyaniline are presented beginning with the initial oxidation of aniline by F. Ferdinand Runge in 1834 and concluding with the first electrochemical oxidation of aniline by Henry Letheby in 1862. In the process, the reports of aniline oxidation products between 1834 and 1862 are evaluated and discussed in light of modern knowledge, highlighting the various historical contributions to the current field of conjugated polymers. Finally, an initial argument for polyaniline as the first synthetic organic polymer is presented. https://riviste.fupress.net/index.php/subs/article/view/30polyanilineaniline blackemeraldineconjugated polymersoxidative polymerization
collection DOAJ
language English
format Article
sources DOAJ
author Seth C. Rasmussen
spellingShingle Seth C. Rasmussen
The Early History of Polyaniline: Discovery and Origins
Substantia
polyaniline
aniline black
emeraldine
conjugated polymers
oxidative polymerization
author_facet Seth C. Rasmussen
author_sort Seth C. Rasmussen
title The Early History of Polyaniline: Discovery and Origins
title_short The Early History of Polyaniline: Discovery and Origins
title_full The Early History of Polyaniline: Discovery and Origins
title_fullStr The Early History of Polyaniline: Discovery and Origins
title_full_unstemmed The Early History of Polyaniline: Discovery and Origins
title_sort early history of polyaniline: discovery and origins
publisher Firenze University Press
series Substantia
issn 2532-3997
publishDate 2017-10-01
description Prior to the discovery of its conductive properties in the 1960s, polyaniline was studied and applied as a variety of colored materials and dyes. The history of the discovery and origins of polyaniline are presented beginning with the initial oxidation of aniline by F. Ferdinand Runge in 1834 and concluding with the first electrochemical oxidation of aniline by Henry Letheby in 1862. In the process, the reports of aniline oxidation products between 1834 and 1862 are evaluated and discussed in light of modern knowledge, highlighting the various historical contributions to the current field of conjugated polymers. Finally, an initial argument for polyaniline as the first synthetic organic polymer is presented.
topic polyaniline
aniline black
emeraldine
conjugated polymers
oxidative polymerization
url https://riviste.fupress.net/index.php/subs/article/view/30
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