catena-Poly[[[aquacopper(II)]-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide-κ2N2:N2′]] dichloride monohydrate]

catena-Poly[[[aquacopper(II)]-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide-κ2N2:N2′]] dichloride monohydrate]

In the title compound, {[Cu(C10H14N4Se)2(H2O)]Cl2·H2O}n, the CuII ion, lying on a twofold rotation axis, has a square-pyramidal geometry constituted by four N atoms of pyrazolyl groups in the basal plane and an apical O atom of a water molecule. A pair of bis(3,5-dimethyl-1H-pyrazol-4-y...

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Main Authors: Maksym Seredyuk, Yurii S. Moroz, Kateryna O. Znovjyak, Vadim A. Pavlenko, Igor O. Fritsky
Format: Article
Language:English
Published: International Union of Crystallography 2010-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810007403
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spelling doaj-ec53402b115a48ba8ee6341af6df492a2020-11-25T01:35:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664m363m36310.1107/S1600536810007403catena-Poly[[[aquacopper(II)]-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide-κ2N2:N2′]] dichloride monohydrate]Maksym SeredyukYurii S. MorozKateryna O. ZnovjyakVadim A. PavlenkoIgor O. FritskyIn the title compound, {[Cu(C10H14N4Se)2(H2O)]Cl2·H2O}n, the CuII ion, lying on a twofold rotation axis, has a square-pyramidal geometry constituted by four N atoms of pyrazolyl groups in the basal plane and an apical O atom of a water molecule. A pair of bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide ligands bridge the Cu centers into a polymeric double-chain extending along [001]. The chloride anions are involved in intermolecular N—H...Cl and O—H...Cl hydrogen bonds, which link the chains into a three-dimensional network. http://scripts.iucr.org/cgi-bin/paper?S1600536810007403
collection DOAJ
language English
format Article
sources DOAJ
author Maksym Seredyuk
Yurii S. Moroz
Kateryna O. Znovjyak
Vadim A. Pavlenko
Igor O. Fritsky
spellingShingle Maksym Seredyuk
Yurii S. Moroz
Kateryna O. Znovjyak
Vadim A. Pavlenko
Igor O. Fritsky
catena-Poly[[[aquacopper(II)]-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide-κ2N2:N2′]] dichloride monohydrate]
Acta Crystallographica Section E
author_facet Maksym Seredyuk
Yurii S. Moroz
Kateryna O. Znovjyak
Vadim A. Pavlenko
Igor O. Fritsky
author_sort Maksym Seredyuk
title catena-Poly[[[aquacopper(II)]-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide-κ2N2:N2′]] dichloride monohydrate]
title_short catena-Poly[[[aquacopper(II)]-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide-κ2N2:N2′]] dichloride monohydrate]
title_full catena-Poly[[[aquacopper(II)]-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide-κ2N2:N2′]] dichloride monohydrate]
title_fullStr catena-Poly[[[aquacopper(II)]-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide-κ2N2:N2′]] dichloride monohydrate]
title_full_unstemmed catena-Poly[[[aquacopper(II)]-bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide-κ2N2:N2′]] dichloride monohydrate]
title_sort catena-poly[[[aquacopper(ii)]-bis[μ-bis(3,5-dimethyl-1h-pyrazol-4-yl) selenide-κ2n2:n2′]] dichloride monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-04-01
description In the title compound, {[Cu(C10H14N4Se)2(H2O)]Cl2·H2O}n, the CuII ion, lying on a twofold rotation axis, has a square-pyramidal geometry constituted by four N atoms of pyrazolyl groups in the basal plane and an apical O atom of a water molecule. A pair of bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide ligands bridge the Cu centers into a polymeric double-chain extending along [001]. The chloride anions are involved in intermolecular N—H...Cl and O—H...Cl hydrogen bonds, which link the chains into a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810007403
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AT yuriismoroz catenapolyaquacopperiibisamp956bis35dimethyl1hpyrazol4ylselenideamp9542n2n2amp8242dichloridemonohydrate
AT katerynaoznovjyak catenapolyaquacopperiibisamp956bis35dimethyl1hpyrazol4ylselenideamp9542n2n2amp8242dichloridemonohydrate
AT vadimapavlenko catenapolyaquacopperiibisamp956bis35dimethyl1hpyrazol4ylselenideamp9542n2n2amp8242dichloridemonohydrate
AT igorofritsky catenapolyaquacopperiibisamp956bis35dimethyl1hpyrazol4ylselenideamp9542n2n2amp8242dichloridemonohydrate
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