Methanogenesis Potentials: Insights from Mineralogical Diagenesis, SEM and FTIR Features of the Permian Mikambeni Shale of the Tuli Basin, Limpopo Province of South Africa

• Main Authors: George Oluwole Akintola, Francis Amponsah-Dacosta, Steven Rupprecht, Nithyadharseni Palaniyandy, Sphiwe Emmanuel Mhlongo, Wilson Mugera Gitari, Joshua Nosa Edokpayi
• Format: Article
• Language: English
• Published: MDPI AG 2021-06-01
• Series: Minerals
• Subjects: methanogenesis potentials; biogenic methanogenesis; thermal methanogenesis; carbonaceous shale; carboxylic; illitization
• Online Access: https://www.mdpi.com/2075-163X/11/6/651

Carbonaceous shale is more topical than ever before due to the associated unconventional resources of methane. The use of FTIR, SEM-EDX, and mineralogical analyses has demonstrated a promising approach to assess methanogenesis potentials in a more rapid and reliable manner for preliminary prospecting. Representative core samples from the borehole that penetrated the carbonaceous Mikambeni shale Formations were investigated for methanogenesis potentials. The absorption band stretches from 1650 cm⁻¹ to 1220 cm⁻¹ in wavenumber, corresponding to C-O stretching and OH deformation of acetic and phenolic groups in all studied samples, thereby suggesting biogenic methanogenesis. The CO₂ was produced by decarboxylation of organic matter around 2000 cm⁻¹ and 2300 cm⁻¹ and served as a source of the carboxylic acid that dissolved the feldspar. This dissolution process tended to release K⁺ ions, which facilitated the illitization of the smectite minerals. The SEM-EDX spectroscopy depicted a polyframboidal pyrite structure, which indicated a sulfate reduction of pyrite minerals resulting from microbial activities in an anoxic milieu and causes an increase in alkalinity medium that favors precipitation of dolomite in the presence of Ca and Mg as burial depth increases. The contact diagenesis from the proximity of Sagole geothermal spring via Tshipise fault is suggested to have enhanced the transformation of smectite to chlorite via a mixed layer corrensite in a solid-state gradual replacement reaction pathway. The presence of diagenetic chlorite mineral is characteristic of low-grade metamorphism or high diagenetic zone at a temperature around 200 °C to 230 °C and corresponds to thermal breakdown of kerogen to methane at strong absorption band around 2850 cm⁻¹ and 3000 cm⁻¹, indicating thermal methanogenesis.