Surface modification and deuterium retention of tungsten and tungsten-rhenium alloys exposed to deuterium plasma

• Main Authors: Xuexi Zhang, Li Qiao, Hong Zhang, Weizhi Yao, Wenhao He, Yuhong Li, Peng Wang
• Format: Article
• Language: English
• Published: Elsevier 2021-12-01
• Series: Nuclear Materials and Energy
• Subjects: Surface modification; D retention; W; W-Re alloys; TDS
• Online Access: http://www.sciencedirect.com/science/article/pii/S2352179121001460

Surface modification and deuterium (D) retention in pure tungsten (W) and tungsten-rhenium (W-Re) alloys with Re concentration of 1, 3, 5 and 10 wt.% were investigated after exposure to D plasma with an incident energy of 38 eV/D at about 400 K and various fluences ranging from 7.2 × 1023 to 2.6 × 1025 D/m2. It is found that blistering depends strongly on the exposure fluence for both W and W-Re alloy samples. When the D fluence is higher than 2.8 × 1024 D/m2, the surface of W is covered by two types of blisters. One type is small blisters (<2 μm), which appeared in groups only on grains with surface orientation close to (111). The other type is large-sized (>8 μm) and extents over several grains. In the cases of W-Re alloys, only small blisters can be observed on their surface. The blisters on the surface of W-Re alloys preferentially appeared on grains with surface orientation close to (111). Cross-section views of blisters show that the blisters on W-Re alloys always originate from intra-granular cavities. The small and large blisters on W originate from intra- and inter-granular cavities, respectively. The surface blistering fluence threshold for W-Re alloys is lower than for W. For both types of materials, rupture of blisters occurs if the underlying crack reaches the surface at the edge of a blister. The number of ruptured blisters increases with increasing D fluence. TDS results show that there is an additional high-temperature peak at ∼ 800 K in W-Re alloys. The amount of D released from W and W-Re alloys increases with increasing D fluence. In addition, the accumulation of D in W-Re alloys is not noticeably influenced by the amount of Re doping at the exposure temperature of ∼ 400 K.