Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis

Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis

The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transfo...

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Main Authors: Justyna Czaban-Jóźwiak, Łukasz Woźniak, Artur Ulikowski, Katarzyna Kwiecińska, Adam A. Rajkiewicz, Karol Grela
Format: Article
Language:English
Published: MDPI AG 2018-07-01
Series:Molecules
Subjects:
cross metathesis
cross metathesis (CM)
steroid
POSS
polyhedral oligomeric silsesquioxanes
ruthenium complexes
Online Access:http://www.mdpi.com/1420-3049/23/7/1722
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spelling doaj-eddc8945bf1147bd8b488645286bbb642020-11-24T21:44:40ZengMDPI AGMolecules1420-30492018-07-01237172210.3390/molecules23071722molecules23071722Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross MetathesisJustyna Czaban-Jóźwiak0Łukasz Woźniak1Artur Ulikowski2Katarzyna Kwiecińska3Adam A. Rajkiewicz4Karol Grela5Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PO Box 58, 01-224 Warsaw, PolandInstitute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PO Box 58, 01-224 Warsaw, PolandInstitute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PO Box 58, 01-224 Warsaw, PolandInstitute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PO Box 58, 01-224 Warsaw, PolandInstitute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PO Box 58, 01-224 Warsaw, PolandInstitute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PO Box 58, 01-224 Warsaw, PolandThe scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transformation. The reported transformation was used to prepare selected hybrid steroid-POSS compounds.http://www.mdpi.com/1420-3049/23/7/1722cross metathesiscross metathesis (CM)steroidPOSSpolyhedral oligomeric silsesquioxanesruthenium complexes
collection DOAJ
language English
format Article
sources DOAJ
author Justyna Czaban-Jóźwiak
Łukasz Woźniak
Artur Ulikowski
Katarzyna Kwiecińska
Adam A. Rajkiewicz
Karol Grela
spellingShingle Justyna Czaban-Jóźwiak
Łukasz Woźniak
Artur Ulikowski
Katarzyna Kwiecińska
Adam A. Rajkiewicz
Karol Grela
Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
Molecules
cross metathesis
cross metathesis (CM)
steroid
POSS
polyhedral oligomeric silsesquioxanes
ruthenium complexes
author_facet Justyna Czaban-Jóźwiak
Łukasz Woźniak
Artur Ulikowski
Katarzyna Kwiecińska
Adam A. Rajkiewicz
Karol Grela
author_sort Justyna Czaban-Jóźwiak
title Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
title_short Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
title_full Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
title_fullStr Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
title_full_unstemmed Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis
title_sort modification of polyhedral oligomeric silsesquioxanes (poss) molecules by ruthenium catalyzed cross metathesis
publisher MDPI AG
series Molecules
issn 1420-3049
publishDate 2018-07-01
description The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transformation. The reported transformation was used to prepare selected hybrid steroid-POSS compounds.
topic cross metathesis
cross metathesis (CM)
steroid
POSS
polyhedral oligomeric silsesquioxanes
ruthenium complexes
url http://www.mdpi.com/1420-3049/23/7/1722
work_keys_str_mv AT justynaczabanjozwiak modificationofpolyhedraloligomericsilsesquioxanespossmoleculesbyrutheniumcatalyzedcrossmetathesis
AT łukaszwozniak modificationofpolyhedraloligomericsilsesquioxanespossmoleculesbyrutheniumcatalyzedcrossmetathesis
AT arturulikowski modificationofpolyhedraloligomericsilsesquioxanespossmoleculesbyrutheniumcatalyzedcrossmetathesis
AT katarzynakwiecinska modificationofpolyhedraloligomericsilsesquioxanespossmoleculesbyrutheniumcatalyzedcrossmetathesis
AT adamarajkiewicz modificationofpolyhedraloligomericsilsesquioxanespossmoleculesbyrutheniumcatalyzedcrossmetathesis
AT karolgrela modificationofpolyhedraloligomericsilsesquioxanespossmoleculesbyrutheniumcatalyzedcrossmetathesis
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